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The Reactivity of Reduced Graphene Depends on Solvation
dc.contributor.author | Hou, Huilei | |
dc.contributor.author | Merino, Juan P. | |
dc.contributor.author | Criado, Alejandro | |
dc.contributor.author | Hirsch, Andreas | |
dc.contributor.author | Prato, Maurizio | |
dc.date.accessioned | 2024-06-27T16:38:32Z | |
dc.date.available | 2024-06-27T16:38:32Z | |
dc.date.issued | 2019-02-01 | |
dc.identifier.citation | Hui-Lei Hou et al 2019 2D Mater. 6 025009 DOI 10.1088/2053-1583/aafd9b | es_ES |
dc.identifier.issn | 2053-1583 | |
dc.identifier.uri | http://hdl.handle.net/2183/37520 | |
dc.description.abstract | [Abstract] The reactivity of reduced graphene sheets (graphenide), obtained by dissolution of graphite intercalation compounds, in particular KC8, was systemically studied by cova-lent functionalization with 4-fluorobenzenediazonium tetrafluoroborate and 4-iodoaniline in different solvents (5 pure and 7 solvents with addition of K+ chelating agents). Interestingly, proper solvation of the potassium cations was beneficial to the covalent functionalization, while excessive solvation led to destabilization and floccula-tion, with decreased reactivity of graphenide. The results were confirmed by scanning Raman spectroscopy (SRS) and x-ray photoelectron spectroscopy (XPS). | es_ES |
dc.description.sponsorship | M Prato is the recipient of the AXA Chair (2016–2023). A Criado thanks MINECO for his researcher grant (Juan de la Cierva—Incorporación). This work was supported by the EU H2020-SGA-FET-GRAPHENE-2017 (no. 785219) and EU H2020-MSCA-RISE-2016 (no. 734381). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | IOP Publishing | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/785219 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/734381 | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/IJCI-2016-31113/ES/ | es_ES |
dc.relation.uri | https://doi.org/10.1088/2053-1583/aafd9b | es_ES |
dc.rights | Atribución 3.0 | |
dc.rights.uri | https://creativecommons.org/licenses/by/3.0/ | |
dc.subject | Graphene | es_ES |
dc.subject | Graphenide | es_ES |
dc.subject | Reactivity | es_ES |
dc.subject | Solvation | es_ES |
dc.title | The Reactivity of Reduced Graphene Depends on Solvation | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | 2D Materials | es_ES |
UDC.volume | 6 | es_ES |
UDC.issue | 2 | es_ES |
UDC.startPage | Article 025009 | es_ES |
dc.identifier.doi | 10.1088/2053-1583/aafd9b |
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