The Reactivity of Reduced Graphene Depends on Solvation
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The Reactivity of Reduced Graphene Depends on SolvationDate
2019-02-01Citation
Hui-Lei Hou et al 2019 2D Mater. 6 025009 DOI 10.1088/2053-1583/aafd9b
Abstract
[Abstract] The reactivity of reduced graphene sheets (graphenide), obtained by dissolution of graphite intercalation compounds, in particular KC8, was systemically studied by cova-lent functionalization with 4-fluorobenzenediazonium tetrafluoroborate and 4-iodoaniline in different solvents (5 pure and 7 solvents with addition of K+ chelating agents). Interestingly, proper solvation of the potassium cations was beneficial to the covalent functionalization, while excessive solvation led to destabilization and floccula-tion, with decreased reactivity of graphenide. The results were confirmed by scanning Raman spectroscopy (SRS) and x-ray photoelectron spectroscopy (XPS).
Keywords
Graphene
Graphenide
Reactivity
Solvation
Graphenide
Reactivity
Solvation
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Atribución 3.0
ISSN
2053-1583