Listar GI-REACT! - Artigos por título
Mostrando ítems 51-70 de 106
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Integrated Valorization of Sargassum Muticum in Biorefineries
(Elsevier, 2020-05-24)[Abstract] Marine macroalgae represent an excellent raw material for the production of bioactives, adsorbents, plant biostimulants, soil fertilizers and biogas. The success in the exploitation of seaweeds depends on their ... -
Introducing Hyaluronic Acid into Supramolecular Polymers and Hydrogels
(American Chemical Society, 2021-10-18)[Abstract] The use of supramolecular polymers to construct functional biomaterials is gaining more attention due to the tunable dynamic behavior and fibrous structures of supramolecular polymers, which resemble those found ... -
Investigations into the effects of linker length elongation on the behaviour of calcium-responsive MRI probes
(Royal Society of Chemistry, 2019-07-25)[Abstract] Understanding the relationship between chemical structure and the effectiveness of bioresponsive magnetic resonance imaging (MRI) contrast agents can offer help to identify key components required for the future ... -
Lead(II) complexes of lateral macrobicyclic receptors that incorporate a crown moiety and a pyridine head unit
(Wiley, 2010-11)[Abstract] The coordinative properties towards lead(II) of two lateral macrobicyclic receptors that incorporate either a 1,10‐diaza‐[15]crown‐5 (L7) or a 4,13‐diaza‐[18]crown‐6 (L8) fragment are reported. Spectrophotometric ... -
Macrocyclic receptor showing improved PbII/ZnII and PbII/CaII selectivities
(Wiley, 2010-05-31)[Abstract] Herein we report on the macrocyclic receptor N,N′‐bis[(6‐carboxy‐2‐pyridyl)methyl]‐1,10‐diaza‐15‐crown‐5 (H2bp15c5) and its coordination properties towards ZnII, CdII, PbII, and CaII. The stability constants of ... -
Magnetic anisotropies in rhombic lanthanide(III) complexes do not conform to Bleaney’s theory
(American Chemical Society, 2016-04-04)[Abstract] We report a complete set of magnetic susceptibilities of lanthanide complexes with a macrocyclic ligand based on a 3,6,10,13-tetraaza-1,8(2,6)-dipyridinacyclotetradecaphane platform containing four hydroxyethyl ... -
Mechanical Stability Is Key for Large-Scale Implementation of Photocatalytic Surface-Attached Film Technologies in Water Treatment
(Frontiers, 2021-10-18)[Abstract] Replacement of classical tertiary water treatment by chemical-free sunlight-driven photocatalytic units has been often proposed. Photocatalysts are required to be cost-effective, inert, chemically stable, reusable, ... -
Modeling the OEC with two new biomimetic models: preparations, structural characterization, and water photolysis studies of a Ba–Mn box type complex and a Mn4N6 planar-diamond cluster
(MDPI, 2018-09-07)[Abstract] The oxygen-evolving complex (OEC) is the native enzyme that catalyzes the oxidation of water in natural photosynthesis. Two new classes of manganese cluster complexes of formula Ba2Mn2L12(H3L1)2(CH3OH)4 1 and ... -
On the Dissociation Pathways of Copper Complexes Relevant as Pet Imaging Agents
(Elsevier, 2022)[Abstract] Several bifunctional chelators have been synthesized in the last years for the development of new 64Cu-based PET agents for in vivo imaging. When designing a metal-based PET probe, it is important to achieve ... -
Optimising the relaxivities of Mn2+ complexes by targeting human serum albumin (HSA)
(Royal Society of Chemistry, 2017-07-14)[Abstract] We report two novel macrocyclic ligands based on the 1,4-DO2AM platform (1,4-DO2AM = 2,2′-(1,4,7,10-tetraazacyclododecane-1,4-diyl)diacetamide) and containing two benzyl groups attached either to the nitrogen ... -
Paramagnetic lanthanide chelates for multicontrast MRI
(Royal Society of Chemistry, 2016-06-02)[Abstract] The preparation of a paramagnetic chelator that serves as a platform for multicontrast MRI, and can be utilized either as a T1-weighted, paraCEST or 19F MRI contrast agent is reported. Its europium(III) complex ... -
Phosphate and polyphosphate anion recognition by a dinuclear copper(ii) complex of an unsymmetrical squaramide
(Royal Society of Chemistry, 2019-05-29)[Abstract] In the search for receptors suitable for the recognition of phosphate or polyphosphate anions, a new unsymmetrical squaramide-based ligand bearing dipicolylamine (dpa) and ethylpiperazine units (L) was designed ... -
Photo-Immobilization of Proteins on Carbons
(Elsevier, 2019-11-13)[Abstract] The photofunctionalization of three different carbons with two proteins was studied at room temperature. Water solutions of bovine serum albumin, BSA, and α-amylase, AA, were photolyzed at 21 °C in the presence ... -
Plastic Debris in Lakes and Reservoirs
(Springer Nature, 2023)[Abstract] Plastic debris is thought to be widespread in freshwater ecosystems globally1. However, a lack of comprehensive and comparable data makes rigorous assessment of its distribution challenging2,3. Here we present ... -
Preparation, Characterization and Testing of a Bulky Non-supported Photocatalyst for Water Pollution Abatement
(Elsevier, 2023-03-15)[Abstract] An innovative bulky photocatalyst for water decontamination has been developed. The semiconductor (TiO2) is homogeneously distributed in an aggregating material through the whole piece. This design prevents the ... -
Receptor versus counterion: capability of N,N′‐Bis(2‐aminobenzyl)‐diazacrowns for giving endo‐ and/or exocyclic coordination of ZnII
(Wiley, 2007-03-20)[Abstract] The structure of ZnII complexes with receptors L1 and L2[L1 = N,N′‐bis(2‐aminobenzyl)‐1,10‐diaza‐15‐crown‐5 and L2 = N,N′‐bis(2‐aminobenzyl)‐4,13‐diaza‐18‐crown‐6] was studied both in the solid state and in ... -
Recognition of AMP, ADP and ATP through cooperative binding by Cu(II) and Zn(II) complexes containing urea and/or phenylboronic acid moieties
(MDPI, 2018)[Abstract] We report a series of Cu(II) and Zn(II) complexes with different ligands containing a dipicolyl unit functionalized with urea groups that may contain or not a phenylboronic acid function. These complexes were ... -
Reinforced Ni(ɪɪ)-Cyclam Derivatives as Dual ¹H/¹⁹F MRI Probes
(Royal Society of Chemistry, 2019-03-11)[Abstract] Reinforced cross-bridged Ni²⁺-cyclam complexes were functionalised with pendant arms containing both amide protons and CF₃ groups that lead to a dual ¹H/¹⁹F response. The resulting complexes possess very high ... -
Relevance of Palladium to Radiopharmaceutical Development Considering Enhanced Coordination Properties of TE1PA
(Wiley, 2022-06-10)[Abstract] The limited use of palladium-103 and -109 radionuclides for molecular radiotherapy is surely due to the lack of appropriate ligands capable of fulfilling all criteria required for application in nuclear medicine. ... -
Removal of Emerging Pollutants by a 3-Step System: Hybrid Digester, Vertical Flow Constructed Wetland and Photodegradation Post-treatments
(Elsevier, 2022-06-22)[Abstract] The removal of emerging pollutants from municipal wastewater was studied for the first time using a three-step pilot-scale system: 1) hybrid digester (HD) as first step, 2) subsurface vertical flow constructed ...