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The role of the capping bond effect on pyclen natY3+/90Y3+ chelates: full control of the regiospecific N-functionalization makes the difference
dc.contributor.author | Le Fur, Mariane | |
dc.contributor.author | Beyler, Maryline | |
dc.contributor.author | Molnár, Enikö | |
dc.contributor.author | Fougère, Olivier | |
dc.contributor.author | Esteban-Gómez, David | |
dc.contributor.author | Tircsó, Gyula | |
dc.contributor.author | Platas-Iglesias, Carlos | |
dc.contributor.author | Lepareur, Nicolas | |
dc.contributor.author | Rousseaux, Olivier | |
dc.contributor.author | Tripier, Raphaël | |
dc.date.accessioned | 2018-11-28T11:47:49Z | |
dc.date.available | 2018-11-28T11:47:49Z | |
dc.date.issued | 2017-09-07 | |
dc.identifier.citation | The role of the capping bond effect on pyclen natY3+/90Y3+ chelates: full control of the regiospecific N-functionalization makes the difference. M. Le Fur, M. Beyler, E. Molnár, O. Fougère, D. Esteban-Gómez, G. Tircsó, C. Platas-Iglesias, N. Lepareur, O. Rousseaux and R. Tripier, Chem. Commun., 2017, 53, 9534–9537. | es_ES |
dc.identifier.issn | 1359-7345 | |
dc.identifier.issn | 1364-548X | |
dc.identifier.uri | http://hdl.handle.net/2183/21395 | |
dc.description.abstract | [Abstract] Thanks to a smart regiospecific N-functionalization, a pyclen based ligand bearing one picolinate and two acetate arms organized in a dissymmetric manner was synthesized for Y3+ complexation, and compared to its symmetric analogue. The nature of the capping bonds around the metal coordination environment has a dramatic effect on the properties of the chelate, the natY3+ and 90Y3+ dissymmetric derivatives presenting enhanced thermodynamic stability and kinetic inertness. | es_ES |
dc.description.sponsorship | Hungarian Scientific Research Fund; NKFIH K-120224 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.uri | https://doi.org/10.1039/C7CC05088G | es_ES |
dc.subject | Thermodynamic stability | es_ES |
dc.subject | DFT calculations | es_ES |
dc.subject | Yttrium complexes | es_ES |
dc.subject | Pyclen ligands | es_ES |
dc.subject | Radiotherapy | es_ES |
dc.title | The role of the capping bond effect on pyclen natY3+/90Y3+ chelates: full control of the regiospecific N-functionalization makes the difference | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | Chemical Communications | es_ES |
UDC.volume | 53 | es_ES |
UDC.issue | 69 | es_ES |
UDC.startPage | 9534 | es_ES |
UDC.endPage | 9537 | es_ES |
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