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Narrowing the Tolerance Factor Limits for Hybrid Organic-Inorganic Dicyanamide-Perovskites
(Elsevier, 2022-10-11)
[Abstract] In this work we focus in setting the limits of the tolerance factor and the size of the A-cations that stabilize the perovskite structure in hybrid dicyanamide compounds [A][Mn(dca)3]. For this purpose, we propose ...
Simple and Low-Cost Footstep Energy-Recover Barocaloric Heating and Cooling Device
(MDPI, 2021-10-10)
[Abstract] In this work, we design, build, and test one of the very first barocaloric devices. The here presented device can recover the energy generated by an individual’s footstep and transform it into barocaloric heating ...
Dicyanamide-Perovskites at the Edge of Dense Hybrid Organic–Inorganic Materials
(Elsevier, 2021-12-24)
[Abstract] Hybrid organic–inorganic ABX3 perovskites with dicyanamide-ligands (dca: [N(CN)2]−) on the X-site are emerging as a distinct group of materials courtesy of their multifunctional properties. Here we present an ...
@thermogramer: Thermal Imaging as a Tool for Science Communication and E-Learning in Social Media
(MDPI, 2022-03-07)
[Abstract] The COVID-19 pandemic boosted the presence of thermal cameras in our society. These devices are becoming cheaper and smaller and can even be plugged in our smartphones. Therefore, soon enough everybody will have ...
Discovery of Colossal Breathing-Caloric Effect under Low Applied Pressure in the Hybrid Organic–Inorganic MIL-53(Al) Material
(American Chemical Society, 2022-03-30)
[Abstract] In this work, “breathing-caloric” effect is introduced as a new term to define very large thermal changes that arise from the combination of structural changes and gas adsorption processes occurring during ...
Near-Room-Temperature Reversible Giant Barocaloric Effects in [(CH₃)₄N]Mn[N₃]₃ Hybrid Perovskite
(Royal Society of Chemistry, 2020-09-25)
[Abstract] We report giant reversible barocaloric effects in [(CH₃)₄N]Mn[N₃]₃ hybrid organic–inorganic perovskite, near its first-order cubic-monoclinic structural phase transition at 𝑇₀ ∼ 305 K. When driving the transition ...
Anomalous and Colossal Thermal Expansion, Photoluminescence, and Dielectric Properties in Lead Halide-Layered Perovskites With Cyclohexylammonium and Cyclopentylammonium Cations
(Elsevier, 2022-06-03)
[Abstract] A detailed study of lead halide-layered perovskites with general formula A2PbX4 (where A is cyclohexylammonium (CHA) or cyclopentylammonium (CPA) cation and X is Cl− or Br− anion) is presented. Using variable ...
Coexistence of magnetic and electrical order in the new perovskite-like (C3N2H5)[Mn(HCOO)3] formate
(The Royal Society of Chemistry, 2013-09)
[Abstract] In this work we further the structural characterization of the recently discovered (C3N2H5)[Mn(HCOO)3] metal–organic framework with perovskite-like structure, and we present its magnetic and dielectric properties ...
Structural, Thermal and Functional Properties of a Hybrid Dicyanamide-Perovskite Solid Solution
(MDPI, 2022-06-18)
[Abstract]: In Solid-State Chemistry, a well-known route to obtain new compounds and modulate their
properties is the formation of solid solutions, a strategy widely exploited in the case of classical inorganic
perovskites ...
Structure and thermal property relationships in the thermomaterial di-n-butylammonium tetrafluoroborate for multipurpose cooling and cold-storage
(Royal Society of Chemistry, 2023-11-07)
[Abstract]: Nowadays around 46% of food production around the world requires refrigeration, which is generally
provided either by active vapour-compression (based on refrigerants with liquid–gas transitions) or
passive ...