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Light-driven, heterogeneous organocatalysts for C–C bond formation toward valuable perfluoroalkylated intermediates
dc.contributor.author | Filippini, Giacomo | |
dc.contributor.author | Longobardo, Francesco | |
dc.contributor.author | Forster, Luke | |
dc.contributor.author | Criado, Alejandro | |
dc.contributor.author | Di Carmine, Graziano | |
dc.contributor.author | Nasi, Lucia | |
dc.contributor.author | D'Agostino, Carmine | |
dc.contributor.author | Melchionna, Michele | |
dc.contributor.author | Fornasiero, Paolo | |
dc.contributor.author | Prato, Maurizio | |
dc.date.accessioned | 2024-08-07T09:05:13Z | |
dc.date.available | 2024-08-07T09:05:13Z | |
dc.date.issued | 2020-11-11 | |
dc.identifier.citation | Citation: G. Filippini, F. Longobardo, L. Forster, A. Criado, G. Di Carmine, L. Nasi, C. D’Agostino, M. Melchionna, P. Fornasiero, M. Prato, Light-driven, heterogeneous orga-nocatalysts for novel C–C bond formation toward valuable perfluoroalkylated intermediates. Sci. Adv. 6, eabc9923 (2020). | es_ES |
dc.identifier.issn | 2375-2548 (eISSN) | |
dc.identifier.uri | http://hdl.handle.net/2183/38436 | |
dc.description.abstract | The favorable exploitation of carbon nitride (CN) materials in photocatalysis for organic synthesis requires the appropriate fine-tuning of the CN structure. Here, we present a deep investigation of the structure/activity relationship of CN in the photocatalytic perfluoroalkylation of organic compounds. Four types of CN bearing subtle structural differences were studied via conventional characterization techniques and innovative nuclear magnetic resonance (NMR) experiments, correlating the different structures with the fundamental mechanistic nexus and especially highlighting the importance of the halogen bond strength between the reagent and the catalyst surface. The optimum catalyst exhibited an excellent performance, with a very wide reaction scope, and could prominently trigger the model reaction using natural sunlight. The work lays a platform for establishing a new approach in the development of heterogeneous photocatalysts for organic synthesis related to medical, agricultural, and material chemistry. | es_ES |
dc.description.sponsorship | This work was supported by the University of Trieste, INSTM, the Italian Ministry of Education MIUR (cofin Prot. 2017PBXPN4), and the European Commission (DECADE). This work was performed under the Maria de Maeztu Units of Excellence Program from the Spanish State Research Agency grant no.MDM-2017-0720. V. Dal Santo is acknowledged for the DRS measurements. G. Adami and M. Crosera are acknowledged for the ICP-OES analysis. C.D. thanks the EPSRC New Investigator Award (EP/S019138/1) for supporting his research activities. | es_ES |
dc.description.sponsorship | Engineering and Physical Sciences Research Council New Investigator Award; EP/S019138/1 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Association for the Advancement of Science | es_ES |
dc.relation | info:eu-repo/grantAgreement/MIUR/Progetti di Ricerca di Rilevante Interesse Naziona-le 2017/2017PBXPN4/IT/ | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MDM-2017-0720/ES/ | es_ES |
dc.relation.uri | https://doi.org/10.1126/sciadv.abc9923 | es_ES |
dc.rights | Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. Distributed under a Creative Commons Attribution License 4.0 (CC BY). | es_ES |
dc.subject | Graphitic carbon nitride | es_ES |
dc.subject | Hydrogen-peroxide | es_ES |
dc.subject | Oxygen reduction | es_ES |
dc.subject | Photocatalyst | es_ES |
dc.subject | Oxidation | es_ES |
dc.subject | Arenes | es_ES |
dc.subject | NMR | es_ES |
dc.subject | Iodoperfluoroalkylation | es_ES |
dc.subject | Pharmaceuticals | es_ES |
dc.subject | Heteroarenes | es_ES |
dc.subject | Characterization techniques | es_ES |
dc.subject | Structure/activity relationship | es_ES |
dc.title | Light-driven, heterogeneous organocatalysts for C–C bond formation toward valuable perfluoroalkylated intermediates | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | Science Advances | es_ES |
UDC.volume | 6 | es_ES |
UDC.issue | 46 | es_ES |
UDC.startPage | Article eabc9923 | es_ES |
dc.identifier.doi | 10.1126/sciadv.abc9923 |