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Indium(III) as π-acid Catalyst for the Electrophilic Activation of Carbon–Carbon Unsaturated Systems
dc.contributor.author | Pérez Sestelo, José | |
dc.contributor.author | Sarandeses, Luis A. | |
dc.contributor.author | Martínez, Montserrat | |
dc.contributor.author | Alonso-Marañón, Lorena | |
dc.date.accessioned | 2024-01-25T20:26:15Z | |
dc.date.issued | 2018-07-25 | |
dc.identifier.citation | Sestelo, J. P., Sarandeses, L. A., Martínez, M. M., & Alonso-Marañón, L. (2018). Indium(III) as π-acid catalyst for the electrophilic activation of carbon–carbon unsaturated systems. Organic & Biomolecular Chemistry, 16(32), 5733-5747. https://doi.org/10.1039/C8OB01426D | es_ES |
dc.identifier.issn | 1477-0539 | |
dc.identifier.uri | http://hdl.handle.net/2183/35173 | |
dc.description.abstract | [Abstract] This review focuses on the utilization of indium(III) as π-acid for the activation of C–C unsaturated bonds in organic synthesis. In addition to its well-known σ-coordination with carbonyl derivatives, indium(III) undergoes efficient π-coordination with unsaturated systems to trigger nucleophilic addition. Accordingly, indium(III) halides and salts (InX3, X = Cl, Br, I, OTf, ONf, NTf2) have been reported as useful catalysts for a broad range of carbon–carbon and carbon–heteroatom bond formation reactions, including hydrofunctionalization (hydroarylation, hydroamination, hydroalkoxylation, and hydrothiolation), enyne cycloisomerization, and related reactions. In these reactions the counterion has a significant effect on the catalytic activity, and the development of novel In(III) complexes and the generation of highly electrophilic cationic indium(III) species has increased its synthetic applications as a π-acid catalyst. | es_ES |
dc.description.sponsorship | We are grateful to the Spanish Ministerio de Economía y Competividad (CTQ2015-68369-P), Xunta de Galicia (GRC2014/042), and EDRF funds for financial support | es_ES |
dc.description.sponsorship | Xunta de Galicia; GRC2014/042 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry (Gran Bretaña) | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-68369-P/ES/INDIO EN REACCIONES DE ACOPLAMIENTO Y CATALISIS: ESTRUCTURA, REACTIVIDAD Y APLICACIONES SINTETICAS/ | es_ES |
dc.relation.uri | https://doi.org/10.1039/C8OB01426D | es_ES |
dc.rights | © The Royal Society of Chemistry 2018 | es_ES |
dc.title | Indium(III) as π-acid Catalyst for the Electrophilic Activation of Carbon–Carbon Unsaturated Systems | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/embargoedAccess | es_ES |
dc.date.embargoEndDate | 9999-99-99 | es_ES |
dc.date.embargoLift | 10007-06-07 | |
UDC.journalTitle | Organic and Biomolecular Chemistry | es_ES |
UDC.volume | 16 (2018) | es_ES |
UDC.issue | 32 (28 August) | es_ES |
UDC.startPage | 5733 | es_ES |
UDC.endPage | 5747 | es_ES |
dc.identifier.doi | 10.1039/C8OB01426D |