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dc.contributor.authorGarcía Ben, Javier
dc.contributor.authorGarcía-Fernández, Alberto
dc.contributor.authorDafonte Rodríguez, Pedro
dc.contributor.authorDelgado Ferreiro, Ignacio
dc.contributor.authorCappel, Ute
dc.contributor.authorCastro-García, Socorro
dc.contributor.authorSánchez-Andújar, Manuel
dc.contributor.authorBermúdez-García, Juan Manuel
dc.contributor.authorSeñarís-Rodríguez, M. A.
dc.date.accessioned2023-02-16T20:25:51Z
dc.date.available2023-02-16T20:25:51Z
dc.date.issued2022-10-11
dc.identifier.citationJavier García-Ben, Alberto García-Fernández, Pedro Dafonte-Rodríguez, Ignacio Delgado-Ferreiro, Ute B. Cappel, Socorro Castro-García, Manuel Sánchez-Andújar, Juan Manuel Bermúdez-García, María Antonia Señarís-Rodríguez, Narrowing the tolerance factor limits for hybrid organic-inorganic dicyanamide-perovskites, Journal of Solid State Chemistry, Volume 316, 2022, 123635, ISSN 0022-4596, https://doi.org/10.1016/j.jssc.2022.123635. (https://www.sciencedirect.com/science/article/pii/S0022459622007605)es_ES
dc.identifier.issn0022-4596
dc.identifier.urihttp://hdl.handle.net/2183/32520
dc.description.abstract[Abstract] In this work we focus in setting the limits of the tolerance factor and the size of the A-cations that stabilize the perovskite structure in hybrid dicyanamide compounds [A][Mn(dca)3]. For this purpose, we propose an alternative, simple approach to calculate a more realistic effective ionic radius for the large and anisotropic A-cations often present in these type of compounds. We test the proposed procedure by analysing the crystal structures of [A][Mn(dca)3] dicyanamide hybrids reported in the literature and recalculating the tolerance factors of such compounds, as well as by preparing five new [A][Mn(dca)3] members, discussing also the influence of the A-cation shape in the stability limits of the perovskite structure. Interestingly, such methodology is not only useful to develop new compounds of the emerging family of (multi)functional multi(stimuli)-responsive dicyanamide materials but can also be applied to other hybrid organic-inorganic perovskites and related materials.es_ES
dc.description.sponsorshipAs for financial support, the authors thank Ministerio de Economía y Competitividad MINECO and EU-FEDER (projects MAT2017-86453-R and PDC2021-121076-I00), and Xunta de Galicia for the collaboration agreement “Development of research strategic actions Universidade da Coruña I ​+ ​D ​+ ​i 2021–2022: CICA-Disrupting Projects 2021SEM-A3 (NanoCool). J.G.-B. and J.M.B.-G. acknowledge Xunta de Galicia for Predoctoral and Postdoctoral Fellowships, respectively. I.D.-F thanks Ministerio de Universidades for a FPU Predoctoral Fellowship. A. G.-F. and U.B.C thank the Carl Tryggers foundation and the Göran Gustafsson foundation for financial supportes_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relationinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/MAT2017-86453-R/ES/MATERIALES HIBRIDOS ORGANICO-INORGANICOS PARA APLICACIONES DE REFRIGERACION ECOLOGICAS/es_ES
dc.relationinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PDC2021-121076-I00/ES/es_ES
dc.relation.urihttps://doi.org/10.1016/j.jssc.2022.123635es_ES
dc.rightsAtribución-NoComercial-SinDerivadas 4.0 Internacionales_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectHybrid organic-inorganic perovskiteses_ES
dc.subjectTolerance factores_ES
dc.subjectDicyanamide compoundses_ES
dc.subjectA-cation volumees_ES
dc.subjectPromolecule isosurfacees_ES
dc.titleNarrowing the Tolerance Factor Limits for Hybrid Organic-Inorganic Dicyanamide-Perovskiteses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.accessinfo:eu-repo/semantics/openAccesses_ES
UDC.journalTitleJournal of Solid State Chemistryes_ES
UDC.volume316es_ES
UDC.issueDecember 2022es_ES
UDC.startPage123635es_ES
dc.identifier.doi10.1016/j.jssc.2022.123635


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