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Dicyanamide-Perovskites at the Edge of Dense Hybrid Organic–Inorganic Materials
dc.contributor.author | García Ben, Javier | |
dc.contributor.author | McHugh, Lauren Nicole | |
dc.contributor.author | Bennett, Thomas Douglas | |
dc.contributor.author | Bermúdez-García, Juan Manuel | |
dc.date.accessioned | 2022-03-16T13:36:06Z | |
dc.date.available | 2022-03-16T13:36:06Z | |
dc.date.issued | 2021-12-24 | |
dc.identifier.citation | J. García-Ben, L.N. McHugh, T.D. Bennett, J.M. Bermúdez-García, Dicyanamide-perovskites at the edge of dense hybrid organic–inorganic materials, Coordination Chemistry Reviews. 455 (2022) 214337. https://doi.org/10.1016/j.ccr.2021.214337 | es_ES |
dc.identifier.issn | 0010-8545 | |
dc.identifier.uri | http://hdl.handle.net/2183/30028 | |
dc.description | Financiado para publicación en acceso aberto: Universidade da Coruña/CISUG | es_ES |
dc.description.abstract | [Abstract] Hybrid organic–inorganic ABX3 perovskites with dicyanamide-ligands (dca: [N(CN)2]−) on the X-site are emerging as a distinct group of materials courtesy of their multifunctional properties. Here we present an in-depth analysis of the members of this dicyanamide perovskite family, where the presence of the 5 atom-long dca ligand gives rise to relatively open crystal structures - especially when compared with other dense hybrids such as perovskite formates, and which has a profound influence on their chemistry and properties. We compile the synthetic procedures used to obtain these compounds, along with their chemical and structural properties. In terms of their functional properties, dicyanamide-perovskites have already shown an enormous potential for future applications, such as dielectric or magnetic switches, eco-friendly barocaloric refrigerants at low-pressure and room-temperature, or precursors for oil-recovery nanomaterials and thermoelectric glasses, as reviewed here. Additionally, we highlight several emerging phenomena in this family, and anticipate areas with room for development in the field. | es_ES |
dc.description.sponsorship | This work was financially supported by the Ministerio de Economía y Competitividad (MINECO) and EU-FEDER under the project MAT2017-86453-R, and funding for open access charge was covered by Universidade da Coruña/CISUG J. G.-B. and J. M. B.-G. acknowledges Xunta de Galicia for a Predoctoral and Postdoctoral Fellowships, respectivetly. T.D.B. thanks the Royal Society for a University Research Fellowship (UF150021) and the University of Canterbury Te Whare Wānanga o Waitaha, New Zealand, for a University of Cambridge Visiting Canterbury Fellowship. He would also like to acknowledge, alongside L.N.M, the Leverhulme Trust for a Philip Leverhulme Prize | es_ES |
dc.description.sponsorship | Reino Unido. Royal Society; UF150021 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/MAT2017-86453-R/ES/MATERIALES HIBRIDOS ORGANICO-INORGANICOS PARA APLICACIONES DE REFRIGERACION ECOLOGICAS/ | |
dc.relation.uri | https://doi.org/10.1016/j.ccr.2021.214337 | es_ES |
dc.rights | Atribución-NoComercial-SinDerivadas 4.0 Internacional | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Hybrid organic–inorganic perovskites | es_ES |
dc.subject | Metal-organic frameworks | es_ES |
dc.subject | Multistimuliresponsive and multifunctional materials | es_ES |
dc.subject | Structural distortions | es_ES |
dc.subject | Tolerance factor | es_ES |
dc.title | Dicyanamide-Perovskites at the Edge of Dense Hybrid Organic–Inorganic Materials | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | Coordination Chemistry Reviews | es_ES |
UDC.volume | 455 | es_ES |
UDC.startPage | 214337 | es_ES |
dc.identifier.doi | 10.1016/j.ccr.2021.214337 |
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