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Ferrocenylindium reagents in palladium‐catalyzed cross‐coupling reactions: asymmetric synthesis of planar chiral 2‐aryl oxazolyl and sulfinyl ferrocenes
dc.contributor.author | Mato, Mauro | |
dc.contributor.author | Pérez Caaveiro, Cristina | |
dc.contributor.author | Sarandeses, Luis A. | |
dc.contributor.author | Pérez Sestelo, José | |
dc.date.accessioned | 2018-06-13T11:17:45Z | |
dc.date.available | 2018-06-13T11:17:45Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Ferrocenylindium Reagents in Palladium‐Catalyzed Cross‐Coupling Reactions: Asymmetric Synthesis of Planar Chiral 2‐Aryl Oxazolyl and Sulfinyl Ferrocenes. M. Mato, C. Pérez-Caaveiro, L. A. Sarandeses, J. Pérez Sestelo, Adv. Synth. Catal. 2017, 359, 1388. | es_ES |
dc.identifier.issn | 1615-4150 | |
dc.identifier.issn | 1615-4169 | |
dc.identifier.uri | http://hdl.handle.net/2183/20808 | |
dc.description.abstract | [Abstract] The preparation of ferrocenylindium species and palladium‐catalyzed cross-coupling reactions for the synthesis of monosubstituted and planar chiral 1,2‐disubstituted ferrocenes is described. Triferrocenylindium reagents (Fc3In) are efficiently prepared in a one‐pot procedure from ferrocenes by lithiation and transmetallation to indium using InCl3. The palladium‐catalyzed cross‐coupling reactions of Fc3In (40 mol%) with a variety of organic electrophiles (aryl, heteroaryl, benzyl, alkenyl and acyl halides) in THF at 80 °C overnight provided a wide variety of monosubstituted ferrocenes in good to excellent yields. This methodology allowed the stereoselective synthesis of planar chiral 2‐aryl‐1 oxazolylferrocenes and 2‐aryl‐1‐sulfinylferrocenes, which are of interest in asymmetric catalysis. | es_ES |
dc.description.sponsorship | Ministerio de Economía y Competividad; CTQ2015‐68369‐P | es_ES |
dc.description.sponsorship | Galicia. Consellería de Cultura, Educación e Ordenación Universitaria; GRC2014/042 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley | es_ES |
dc.relation.uri | https://doi.org/10.1002/adsc.201601397 | es_ES |
dc.rights | This is the peer reviewed version of the following article: Ferrocenylindium Reagents in Palladium‐Catalyzed Cross‐Coupling Reactions: Asymmetric Synthesis of Planar Chiral 2‐Aryl Oxazolyl and Sulfinyl Ferrocenes. M. Mato, C. Pérez-Caaveiro, L. A. Sarandeses, J. Pérez Sestelo, Adv. Synth. Catal. 2017, 359, 1388, which has been published in final form at https://doi.org/10.1002/adsc.201601397. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | es_ES |
dc.subject | Asymmetric synthesis | es_ES |
dc.subject | Cross-coupling | es_ES |
dc.subject | Ferrocene ligands | es_ES |
dc.subject | Indium | es_ES |
dc.subject | Palladium | es_ES |
dc.title | Ferrocenylindium reagents in palladium‐catalyzed cross‐coupling reactions: asymmetric synthesis of planar chiral 2‐aryl oxazolyl and sulfinyl ferrocenes | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | Advanced Synthesis & Catalysis | es_ES |
UDC.volume | 359 | es_ES |
UDC.issue | 8 | es_ES |
UDC.startPage | 1388 | es_ES |
UDC.endPage | 1393 | es_ES |
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