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Triorganoindium reagents in Rh-catalyzed C–H activation/C–C cross-coupling reactions of 2-arylpyridines
(MDPI, 2018-06-29)
[Abstract] The activation of C–H bonds through catalytic reactions using transition metals is an important challenge in organic chemistry in which the intermediates are related to those produced in the classical cross-coupling ...
Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions
(Royal Society of Chemistry, 2018-02-11)
[Abstract] Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in ...
Indium(III)-Catalyzed Synthesis of Benzo[b]furans by Intramolecular Hydroalkoxylation of ortho-Alkynylphenols: Scope and Mechanistic Insights
(American Chemical Society (ACS), 2018-06-12)
[Abstract] Indium(III) halides catalyze the hydroalkoxylation reaction of ortho-alkynylphenols to afford benzo[b]furans in good yields. The reaction proceeds with 5-endo-dig regioselectivity with a variety of phenols ...
Indium(III) as π-acid Catalyst for the Electrophilic Activation of Carbon–Carbon Unsaturated Systems
(Royal Society of Chemistry (Gran Bretaña), 2018-07-25)
[Abstract] This review focuses on the utilization of indium(III) as π-acid for the activation of C–C unsaturated bonds in organic synthesis. In addition to its well-known σ-coordination with carbonyl derivatives, indium(III) ...
Synthesis of Fused Chromenes by the Indium(III)-Catalyzed Cascade Hydroarylation/Cycloisomerization Reactions of Polyyne-Type Aryl Propargyl Ethers
(Royal Society of Chemistry (Gran Bretaña), 2018-06-15)
[Abstract] Fused 2H-chromenes are prepared by the cascade hydroarylation/cycloisomerization reactions of polyyne-type aryl propargyl ethers using indium(III) catalysis. The transformation proceeds with 6-endo-dig ...