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Structural, Thermal and Functional Properties of a Hybrid Dicyanamide-Perovskite Solid Solution
dc.contributor.author | García Ben, Javier | |
dc.contributor.author | Salgado-Beceiro, Jorge | |
dc.contributor.author | Delgado Ferreiro, Ignacio | |
dc.contributor.author | Dafonte Rodríguez, Pedro | |
dc.contributor.author | López-Beceiro, Jorge | |
dc.contributor.author | Artiaga, Ramón | |
dc.contributor.author | Castro-García, Socorro | |
dc.contributor.author | Sánchez-Andújar, Manuel | |
dc.contributor.author | Bermúdez-García, Juan Manuel | |
dc.contributor.author | Señarís-Rodríguez, M. A. | |
dc.date.accessioned | 2024-07-09T12:09:23Z | |
dc.date.available | 2024-07-09T12:09:23Z | |
dc.date.issued | 2022-06-18 | |
dc.identifier.citation | García-Ben, J.; Salgado-Beceiro, J.; Delgado-Ferreiro, I.; Dafonte-Rodríguez, P.; López-Beceiro, J.; Artiaga, R.; Castro-García, S.; Sánchez-Andújar, M.; Bermúdez-García, J.M.; Señarís-Rodríguez, M.A. Structural, Thermal and Functional Properties of a Hybrid Dicyanamide-Perovskite Solid Solution. Crystals 2022, 12, 860. https://doi.org/10.3390/cryst12060860 | es_ES |
dc.identifier.issn | 2073-4352 | |
dc.identifier.uri | http://hdl.handle.net/2183/37831 | |
dc.description.abstract | [Abstract]: In Solid-State Chemistry, a well-known route to obtain new compounds and modulate their properties is the formation of solid solutions, a strategy widely exploited in the case of classical inorganic perovskites but relatively unexplored among emergent hybrid organic–inorganic perovskites (HOIPs). In this work, to the best of our knowledge, we present the first dicyanamide-perovskite solid solution of [TPrA][Co0.5Ni0.5(dca)3] and study its thermal, dielectric and optical properties, comparing them with those of the parent undoped compounds [TPrA][Co(dca)3] and [TPrA][Ni(dca)3]. In addition, we show that the prepared doped compound can be used as a precursor that, by calcination, allows CNTs with embedded magnetic Ni:Co alloy nanoparticles to be obtained through a fast and much simpler synthetic route than other complex CVD or arc-discharge methods used to obtain this type of material. | es_ES |
dc.description.sponsorship | M.A.S.-R. sincerely thanks Emilio Morán Miguélez for all of his teaching, advice, support, friendship and vital optimism during her Ph.D period in Madrid, as well as throughout the years. We will always remember him with gratitude and with a big smile. From the financial point of view, the authors are thankful for financial support from Ministerio de Economía y Competitividad MINECO and EU-FEDER (projects MAT2017-86453-R and PDC2021-121076-I00) and Xunta de Galicia for the collaboration agreement “Development of research strategic actions UDC I + D + i 2021–2022: CICA-Disrupting Projects 2021SEM-A3 (NanoCool)”. J.G.-B. and J.M.B.-G. acknowledge Xunta de Galicia for Predoctoral and Postdoctoral Fellowships, respectively. I.D.-F thanks Ministerio de Universidades for an FPU Predoctoral Fellowship. The authors also thank Universidade da Coruña/CISUG for funding for the open access of this manuscript. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2017-86453-R/ES/MATERIALES HIBRIDOS ORGANICO-INORGANICOS PARA APLICACIONES DE REFRIGERACION ECOLOGICAS | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PDC2021-121076-I00/ES/IMPLEMENTACION DE MATERIALES HIBRIDOS BAROCALORICOS EN SISTEMAS DE REFRIGERACION MIXTOS CO2-BAROCALORICO | es_ES |
dc.relation.uri | https://doi.org/10.3390/cryst12060860 | es_ES |
dc.rights | Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/ | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | Hybrid perovskites | es_ES |
dc.subject | Solid solution | es_ES |
dc.subject | Dielectric properties | es_ES |
dc.subject | Phase transition | es_ES |
dc.title | Structural, Thermal and Functional Properties of a Hybrid Dicyanamide-Perovskite Solid Solution | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | Crystals | es_ES |
UDC.volume | 12 | es_ES |
UDC.issue | 6 | es_ES |
dc.identifier.doi | https://doi.org/10.3390/cryst12060860 |