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Empowering CO2Eco-Refrigeration With Colossal Breathing-Caloric-Like Effects in MOF-508b
dc.contributor.author | Gelpi Santos, María | |
dc.contributor.author | García Ben, Javier | |
dc.contributor.author | Rodríguez-Hermida, Sabina | |
dc.contributor.author | López-Beceiro, Jorge | |
dc.contributor.author | Artiaga, Ramón | |
dc.contributor.author | Baaliña Insua, Alvaro | |
dc.contributor.author | Romero Gómez, Manuel | |
dc.contributor.author | Romero Gómez, Javier | |
dc.contributor.author | Zaragoza, Sonia | |
dc.contributor.author | Salgado-Beceiro, Jorge | |
dc.contributor.author | Walker, Julian | |
dc.contributor.author | McMonagle, Charles James | |
dc.contributor.author | Castro-García, Socorro | |
dc.contributor.author | Sánchez-Andújar, Manuel | |
dc.contributor.author | Señarís-Rodríguez, M. A. | |
dc.contributor.author | Bermúdez-García, Juan Manuel | |
dc.date.accessioned | 2024-05-16T17:39:20Z | |
dc.date.available | 2024-05-16T17:39:20Z | |
dc.date.issued | 2024 | |
dc.identifier.citation | M. Gelpi, J. García-Ben, S. Rodríguez-Hermida, J. López-Beceiro, R. Artiaga, Á. Baaliña, M. Romero-Gómez, J. Romero-Gómez, S. Zaragoza, J. Salgado-Beceiro, J. Walker, C. J. McMonagle, S. Castro-García, M. Sánchez-Andújar, M. A. Señarís-Rodríguez, J. M. Bermúdez-García, Empowering CO2 Eco-Refrigeration With Colossal Breathing-Caloric-Like Effects in MOF-508b. Adv. Mater. 2024, 36, 2310499. https://doi.org/10.1002/adma.202310499 | es_ES |
dc.identifier.uri | http://hdl.handle.net/2183/36514 | |
dc.description | Financiado para publicación en acceso aberto: Universidade da Coruña/CISUG | es_ES |
dc.description.abstract | [Abstract] Today,≈20% of the electric consumption is devoted to refrigeration; while,≈50% of the final energy is dedicated to heating applications. In this scenario,many cooling devices and heat-pumps are transitioning toward the use ofCO2as an eco-friendly refrigerant, favoring carbon circular economy.Nevertheless, CO2still has some limitations, such as large operatingpressures (70–150 bar) and a critical point at 31°C, which compromisesefficiency and increases technological complexity. Very recently, an innovativebreathing-caloric mechanism in the MIL-53(Al) compound is reported, whichimplies gas adsorption under CO2pressurization boosted by structuraltransitions and which overcomes the limitations of stand-alone CO2. Here,the breathing-caloric-like effects of MOF-508b are reported, surpassing by40% those of MIL-53(Al). Moreover, the first thermometry device operating atroom temperature and under the application of only 26 bar of CO2ispresented. Under those conditions, this material presents values of𝚫������T≈30 K, reaching heating temperatures of 56°C and cooling temperatures of−10°C, which are already useful for space heating, air-conditioning, foodrefrigeration, and freezing applications. | es_ES |
dc.description.sponsorship | The authors are thankful for financial support from the grant PID2021-122532OB-I00 funded by MCIN/AEI/10.13039/501100011033 and by ERDF A way of making Europe, the project PDC2021-121076-I00 funded by MCIN/AEI/10.13039/ 501100011033 and by the European Union Next GenerationEU/PRTR and the project ED431C 2022/39 funded by Xunta de Galicia. This publication is part of the grant RYC2021-033040-I, funded by MCIN/AEI/10.13039/ 501100011033 and from the European Union «NextGenerationEU»/PRTR»and granted to J.M.B.-G. This researcher isal so grateful for the support received by UDC-Inditex InTalent Programme. J.G.-B. acknowledges Xunta de Galicia for Predoctoral Fellowships. The authors thank ESRF for the award of beam time (MA-5145 and A01-2-1291 on BM01). Funding for open access publication granted by Universidade da Coruña/CISUG | es_ES |
dc.description.sponsorship | Xunta de Galicia; ED431C 2022/39 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Wiley | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-122532OB-I00/ES | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-121076-I00/ES | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/RYC2021-033040-I/ES | es_ES |
dc.relation.uri | https://doi.org/10.1002/adma.202310499 | es_ES |
dc.rights | © 2023 The Authors. Advanced Materials published by Wiley-VCH GmbH. This is an open access article under the terms of the CreativeCommons Attribution-NonCommercial-NoDerivsLicense | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
dc.subject | Barocaloric | es_ES |
dc.subject | Breathing-caloric | es_ES |
dc.subject | Metal–organic frameworks | es_ES |
dc.subject | Thermomaterials | es_ES |
dc.subject | Thermometry | es_ES |
dc.title | Empowering CO2Eco-Refrigeration With Colossal Breathing-Caloric-Like Effects in MOF-508b | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | Advanced Materials | es_ES |
UDC.volume | 36 | es_ES |
UDC.issue | 36 | es_ES |
UDC.startPage | 2310499 | es_ES |
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