Experimental and Theoretical Study on Physical Properties of the Systems Dimethyl Carbonate and Diethyl Carbonate + Pentanol Isomers
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Experimental and Theoretical Study on Physical Properties of the Systems Dimethyl Carbonate and Diethyl Carbonate + Pentanol IsomersAuthor(s)
Date
2023-07-14Citation
Montserrat Domínguez-Pérez, Luisa Segade, Oscar Cabeza, Pablo Ligero, Sandra García-Garabal, Experimental and theoretical study on physical properties of the systems dimethyl carbonate and diethyl carbonate + pentanol isomers, Journal of Molecular Liquids, Volume 386, 2023, 122516, ISSN 0167-7322, https://doi.org/10.1016/j.molliq.2023.122516. (https://www.sciencedirect.com/science/article/pii/S016773222301320X)
Abstract
[Abstract] In many industrial applications that involve solvents, the knowledge of both thermodynamics properties and transport properties play an important role in the design, sustainability, and optimization of processes in different fields of study. However, it is a fact that there is a lack of data and predictive models for the develop of future applications. Taking this into account, in this work we studied the physical properties of carbonates and pentanol isomers as well as their mixtures due to the versality of these solvents in many processes. We present measurements of densities (ρ) and excess molar volumes and enthalpies (VmE, HmE) at 298.15 K for the systems dimethyl or diethyl carbonate + pentanol isomers; and specifically for the systems with diethyl carbonate the surface tensions (σ ) and the surface tension deviations (δσ) at 298.15 K and the viscosities (η), dynamic viscosity deviations (Δη), refractive indexes (nD) and the changes in the refractive index (ΔnD) at 298.15 and 308.15 K. Different theoretical models were applied to obtained data for surface tensions and refractive indexes.
Keywords
Dimethyl carbonate
Diethyl carbonate
Pentanol isomers
Physical properties
Diethyl carbonate
Pentanol isomers
Physical properties
Description
Financiado para publicación en acceso aberto: Universidade da Coruña/CISUG
Editor version
Rights
Atribución 4.0 Internacional
ISSN
0167-7322