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Synthesis and Structural Analysis of Push-Pull Imidazole-Triazole Based Fluorescent Bifunctional Chemosensor for CU2+ and FE2+ Detection
(Elsevier, 2022-07)
[Abstract] Fluorescent imidazole-triazole based ligands L1 and L2 have been designed as chemical push-pull chemosensors for divalent metal ions and synthesized through palladium-catalyzed cross-coupling reactions using ...
Rigidified Derivative of the Non-macrocyclic Ligand H₄OCTAPA for Stable Lanthanide(III) Complexation
(American Chemical Society, 2022-03-11)
[Abstract] The stability constants of lanthanide complexes with the potentially octadentate ligand CHXOCTAPA4–, which contains a rigid 1,2-diaminocyclohexane scaffold functionalized with two acetate and two picolinate ...
An Efficient Green Photo-Fenton System for the Degradation of Organic Pollutants. Kinetics of Propranolol Removal From Different Water Matrices
(Elsevier, 2022-01-06)
[Abstract] We report on the degradation of aqueous propranolol (PRO) in a heterogeneous system with natural iron oxide (N.I.O.) and oxalic acid (OAA) under near UV–Vis irradiation. Photolysis experiments showed ca. 65% ...
A Snapshot on the Occurrence and Risk Assessment of Organic Pollutants in an Urban River
(MDPI, 2022-12-22)
[Abstract] A snapshot screening was carried out in an urban river at the end of a dry period in the water and sediments to assess the presence and environmental risk for the following CECs: paracetamol, ibuprofen, diclofenac, ...
Removal of Emerging Pollutants by a 3-Step System: Hybrid Digester, Vertical Flow Constructed Wetland and Photodegradation Post-treatments
(Elsevier, 2022-06-22)
[Abstract] The removal of emerging pollutants from municipal wastewater was studied for the first time using a three-step pilot-scale system: 1) hybrid digester (HD) as first step, 2) subsurface vertical flow constructed ...
On the Dissociation Pathways of Copper Complexes Relevant as Pet Imaging Agents
(Elsevier, 2022)
[Abstract] Several bifunctional chelators have been synthesized in the last years for the development of new 64Cu-based PET agents for in vivo imaging. When designing a metal-based PET probe, it is important to achieve ...
Relevance of Palladium to Radiopharmaceutical Development Considering Enhanced Coordination Properties of TE1PA
(Wiley, 2022-06-10)
[Abstract] The limited use of palladium-103 and -109 radionuclides for molecular radiotherapy is surely due to the lack of appropriate ligands capable of fulfilling all criteria required for application in nuclear medicine. ...
Versatile Macrocyclic Platform for the Complexation of [ⁿᵃᵗY/⁹⁰Y]Yttrium and Lanthanide Ions
(American Chemical Society, 2022-04-14)
[Abstract] We report a macrocyclic ligand (H3L6) based on a 3,6,10,13-tetraaza-1,8(2,6)-dipyridinacyclotetradecaphane platform containing three acetate pendant arms and a benzyl group attached to the fourth nitrogen atom ...
Thermodynamic Stability of Mn(II) Complexes with Aminocarboxylate Ligands Analyzed Using Structural Descriptors
(ACS, 2022-08-22)
[Abstract] We present a quantitative analysis of the thermodynamic stabilities of Mn(II) complexes, defined by the equilibrium constants (log KMnL values) and the values of pMn obtained as −log[Mn]free for total metal and ...