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Surprising Complexity of the [Gd(AAZTA)(H2O)2]− Chelate Revealed by NMR in the Frequency and Time Domains
(American Chemical Society, 2021-12-10)
[Abstract] Typically, Ln(III) complexes are isostructural along the series, which enables studying one particular metal chelate to derive the structural features of the others. This is not the case for [Ln(AAZTA)(H2O)x]− ...
Bifunctional Paramagnetic and Luminescent Clays Obtained by Incorporation of Gd³⁺ and Eu³⁺ Ions in the Saponite Framework
(American Chemical Society, 2021-07-08)
[Abstract] A novel bifunctional saponite clay incorporating gadolinium (Gd³⁺) and europium (Eu³⁺) in the inorganic framework was prepared by one-pot hydrothermal synthesis. The material exhibited interesting luminescent ...
Defining the Conditions for the Development of the Emerging Class of Feᴵᴵᴵ-Based MRI Contrast Agents
(Royal Society of Chemistry, 2021-07-26)
[Abstract] Fe(III) complexes are attracting growing interest in chemists developing diagnostic probes for Magnetic Resonance Imaging because they leverage on an endogenous metal and show superior stability. However, in ...