Listar GI-REACT! - Artigos por autor "García-Dopico, María-Victoria"

Mostrando ítems 1-3 de 3

    • A Theoretical Study on the Mechanism of the Base-Promoted Decomposition of N-chloro,N-methylethanolamine 

      Ramos, Daniel R.; Castillo, Raquel; Canle, Moisés; García-Dopico, María-Victoria; Andrés, Juan; Santaballa, J. Arturo (Royal Society of Chemistry (Gran Bretaña), 2009-02-09)
      [Abstract] The first step of the base-promoted decomposition of N-chloro,N-methylethanolamine in aqueous solution (CH3N(Cl)CH2CH2OH + HO−→ imine + Cl− + H2O (+ CH2O) → amine + aldehyde) is investigated at the MP2/6-31++G(d,p) ...

    • Effect of Ionizing Radiation on Human Myeloperoxidase: Reaction With Hydrated Electrons 

      Ramos, Daniel R.; Fernández-Pérez, María-Isabel; Furtmüller, Paul G.; Obinger, Christian; García-Dopico, María-Victoria; Santaballa, J. Arturo; Canle, Moisés (Elsevier, 2021-11-27)
      [Abstract] Myeloperoxidase (MPO) is a myeloid-lineage restricted enzyme largely expressed in the azurophilic granules of neutrophils. It catalyses the formation of reactive oxygen species, mainly hypochlorous acid, ...

    • Understanding the Mechanism of Base-Assisted Decomposition of (N-halo),N-alkylalcoholamines 

      Andrés, Juan; Armesto Barbeito, Xosé Luís; Canle, Moisés; García-Dopico, María-Victoria; Ramos, Daniel R.; Santaballa, J. Arturo (Royal Society of Chemistry (Gran Bretaña), 2003-09-29)
      [Abstract] The base-assisted decomposition of (N-X),N-methylethanolamine (X = Cl, Br) takes place mainly through two concurrent processes: a fragmentation and an intramolecular elimination. The global process follows second ...