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Tautomerization of 2-acetylcyclohexanone in assemblies of cationic surfactants. Nitrosation of the enol.
(Royal Society of Chemistry, 2005)
The kinetic study of the keto-enol interconversion of 2-acetylcyclohexanone (ACHE) has been performed in organic solvents such as dimethylsulfoxide (DMSO), 1-propanol (1-PrOH), 2-propanol (2-PrOH), methanol (MeOH), dioxane, ...
Solvent Effects versus Concentration Effects in determining Rates of Base-catalysed Keto-enol Tautomerization
(Royal Society of Chemistry, 2005)
Solvent effects of homogeneous media (such as solvent-water mixtures) in chemical reactivity may be interpreted as due to solvent polarity and/or molecular structure of solvent molecules. In microheterogeneous media (such ...