• Discovery of Colossal Breathing-Caloric Effect under Low Applied Pressure in the Hybrid Organic–Inorganic MIL-53(Al) Material 

      García Ben, Javier; López-Beceiro, Jorge; Artiaga, Ramón; Salgado-Beceiro, Jorge; Delgado Ferreiro, Ignacio; Kolen'ko, Yury V.; Castro-García, Socorro; Señarís-Rodríguez, M. A.; Sánchez-Andújar, Manuel; Bermúdez-García, Juan Manuel (American Chemical Society, 2022-03-30)
      [Abstract] In this work, “breathing-caloric” effect is introduced as a new term to define very large thermal changes that arise from the combination of structural changes and gas adsorption processes occurring during ...
    • Empowering CO2Eco-Refrigeration With Colossal Breathing-Caloric-Like Effects in MOF-508b 

      Gelpi Santos, María; García Ben, Javier; Rodríguez-Hermida, Sabina; López-Beceiro, Jorge; Artiaga, Ramón; Baaliña Insua, Alvaro; Romero Gómez, Manuel; Romero Gómez, Javier; Zaragoza, Sonia; Salgado-Beceiro, Jorge; Walker, Julian; McMonagle, Charles James; Castro-García, Socorro; Sánchez-Andújar, Manuel; Señarís-Rodríguez, M. A.; Bermúdez-García, Juan Manuel (Wiley, 2024)
      [Abstract] Today,≈20% of the electric consumption is devoted to refrigeration; while,≈50% of the final energy is dedicated to heating applications. In this scenario,many cooling devices and heat-pumps are transitioning ...
    • Near-Room-Temperature Reversible Giant Barocaloric Effects in [(CH₃)₄N]Mn[N₃]₃ Hybrid Perovskite 

      Salgado-Beceiro, Jorge; Silva, Ariel Nonato Almeida de Abreu; Silva, Rosivaldo Xavier da; García-Fernández, Alberto; Sánchez-Andújar, Manuel; Castro-García, Socorro; Stern-Taulats, Enric; Señarís-Rodríguez, M. A.; Moya, Xavier; Bermúdez-García, Juan Manuel (Royal Society of Chemistry, 2020-09-25)
      [Abstract] We report giant reversible barocaloric effects in [(CH₃)₄N]Mn[N₃]₃ hybrid organic–inorganic perovskite, near its first-order cubic-monoclinic structural phase transition at 𝑇₀ ∼ 305 K. When driving the transition ...
    • Raman Spectroscopy Studies on the Barocaloric Hybrid Perovskite [(CH₃)₄N][Cd(N₃)₃] 

      Silva, Rosivaldo Xavier da; Paschoal, Carlos William de Araujo; Santos, Clenilton; García-Fernández, Alberto; Salgado-Beceiro, Jorge; Señarís-Rodríguez, M. A.; Sánchez-Andújar, Manuel; Silva, Ariel Nonato Almeida de Abreu (MDPI, 2020-10-16)
      [Abstract] Temperature-dependent Raman scattering and differential scanning calorimetry were applied to the study of the hybrid organic-inorganic azide-perovskite [(CH₃)₄N][Cd(N₃)₃], a compound with multiple structural ...
    • Simple and Low-Cost Footstep Energy-Recover Barocaloric Heating and Cooling Device 

      García Ben, Javier; Delgado Ferreiro, Ignacio; Salgado-Beceiro, Jorge; Bermúdez-García, Juan Manuel (MDPI, 2021-10-10)
      [Abstract] In this work, we design, build, and test one of the very first barocaloric devices. The here presented device can recover the energy generated by an individual’s footstep and transform it into barocaloric heating ...
    • Structural, Thermal and Functional Properties of a Hybrid Dicyanamide-Perovskite Solid Solution 

      García Ben, Javier; Salgado-Beceiro, Jorge; Delgado Ferreiro, Ignacio; Dafonte Rodríguez, Pedro; López-Beceiro, Jorge; Artiaga, Ramón; Castro-García, Socorro; Sánchez-Andújar, Manuel; Bermúdez-García, Juan Manuel; Señarís-Rodríguez, M. A. (MDPI, 2022-06-18)
      [Abstract]: In Solid-State Chemistry, a well-known route to obtain new compounds and modulate their properties is the formation of solid solutions, a strategy widely exploited in the case of classical inorganic perovskites ...