Equilibrium constants of triethanolamine in major seawater salts

Use this link to cite
http://hdl.handle.net/2183/14116Collections
- Investigación (FCIE) [1160]
Metadata
Show full item recordTitle
Equilibrium constants of triethanolamine in major seawater saltsAuthor(s)
Date
2006-12Citation
Brandariz I, Castro P, Montes M, Penedo F, Sastre de Vicente ME. Equilibrium constants of triethanolamine in major seawater salts. Mar Chem. 2006;102(3-4):291-9.
Abstract
Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work.
Keywords
Acid–base equilibrium
Pitzer model
Triethanolamine
Potentiometry
Ionic strength
Seawater
Stoichiometric constants
Pitzer model
Triethanolamine
Potentiometry
Ionic strength
Seawater
Stoichiometric constants
Editor version
ISSN
0304-4203