Listar por autor "García-Dopico, María-Victoria"
Mostrando ítems 1-4 de 4
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A Theoretical Study on the Mechanism of the Base-Promoted Decomposition of N-chloro,N-methylethanolamine
Ramos, Daniel R.; Castillo, Raquel; Canle, Moisés; García-Dopico, María-Victoria; Andrés, Juan; Santaballa, J. Arturo (Royal Society of Chemistry (Gran Bretaña), 2009-02-09)[Abstract] The first step of the base-promoted decomposition of N-chloro,N-methylethanolamine in aqueous solution (CH3N(Cl)CH2CH2OH + HO−→ imine + Cl− + H2O (+ CH2O) → amine + aldehyde) is investigated at the MP2/6-31++G(d,p) ... -
Effect of Ionizing Radiation on Human Myeloperoxidase: Reaction With Hydrated Electrons
Ramos, Daniel R.; Fernández-Pérez, María-Isabel; Furtmüller, Paul G.; Obinger, Christian; García-Dopico, María-Victoria; Santaballa, J. Arturo; Canle, Moisés (Elsevier, 2021-11-27)[Abstract] Myeloperoxidase (MPO) is a myeloid-lineage restricted enzyme largely expressed in the azurophilic granules of neutrophils. It catalyses the formation of reactive oxygen species, mainly hypochlorous acid, ... -
Estudio cinético de las reacciones de formación y descomposición de N-CI-Dipéptidos
García-Dopico, María-Victoria (1995) -
Understanding the Mechanism of Base-Assisted Decomposition of (N-halo),N-alkylalcoholamines
Andrés, Juan; Armesto Barbeito, Xosé Luís; Canle, Moisés; García-Dopico, María-Victoria; Ramos, Daniel R.; Santaballa, J. Arturo (Royal Society of Chemistry (Gran Bretaña), 2003-09-29)[Abstract] The base-assisted decomposition of (N-X),N-methylethanolamine (X = Cl, Br) takes place mainly through two concurrent processes: a fragmentation and an intramolecular elimination. The global process follows second ...