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Controlled Binding of Organic Guests by Stimuli-Responsive Macrocycles
dc.contributor.author | Blanco-Gómez, Arturo | |
dc.contributor.author | Cortón, Pablo | |
dc.contributor.author | Barravecchia Prado, Liliana Inés | |
dc.contributor.author | Neira, Iago | |
dc.contributor.author | Pazos, Elena | |
dc.contributor.author | Peinador, Carlos | |
dc.contributor.author | García, Marcos D. | |
dc.date.accessioned | 2022-09-21T07:59:54Z | |
dc.date.available | 2022-09-21T07:59:54Z | |
dc.date.issued | 2020-05-12 | |
dc.identifier.citation | A. Blanco-Gómez, P. Cortón, L. Barravecchia, I. Neira, E. Pazos, C. Peinador and M. D. García, Controlled binding of organic guests by stimuli-responsive macrocycles, Chem. Soc. Rev., 2020, 49, 3834–3862. https://doi.org/10.1039/D0CS00109K | es_ES |
dc.identifier.issn | 1460-4744 | |
dc.identifier.uri | http://hdl.handle.net/2183/31671 | |
dc.description.abstract | [Abstract] Synthetic supramolecular chemistry pursues not only the construction of new matter, but also control over its inherently dynamic behaviour. In this context, classic host–guest chemistry, based on the development of a myriad of macrocyclic receptors with fine-tuned affinities and selectivities, has enormously contributed to the discovery of new chemical function under self-assembly conditions. In turn, the use of molecular switches as control units within host–guest assemblies opened the door for the regulation of their dynamic interactional behaviour, which can be translated into controlled aggregation. In this review, we will focus on different strategies developed for the regulated binding of organic molecules by switchable macrocyclic hosts. As we will see, an appropriate design using stimuli-responsive versions of well-known organic receptors allows the molecular switches implemented within their structures to transform their regulated behaviour from the molecular to the supramolecular level. | es_ES |
dc.description.sponsorship | This research was supported by the Ministerio de Economía y Competitividad (MINECO FEDER, Grant CTQ2016-75629-P), Agencia Estatal de Investigación (AEI) and Fondo Europeo de Desarrollo Regional (FEDER) (CTQ2017-89166-R), and Xunta de Galicia (ED431C 2018/39). E. P. thanks the funding received from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No. 851179), the UDC-Inditex InTalent Programme for her research contract and funding and the Xunta de Galicia for the Oportunius Programme. I. N. thanks the MECD (FPU program) for financial support | es_ES |
dc.description.sponsorship | Xunta de Galicia; ED431C 2018/39 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/851179 | es_ES |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-75629-P/ES/NUEVOS SISTEMAS SUPRAMOLECULARES DINAMICOS. ESTABILIZACION SELECTIVA DE G-QUADRUPLEXES CON ESTRUCTURAS METALOCICLICAS/ | |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/CTQ2017-89166-R/ES/HERRAMIENTAS PEPTIDICAS PARA APLICACIONES BIOLOGICAS: SENSORES INTELIGENTES PARA ESTUDIAR NITRACION DE PROTEINAS Y NANOMATERIALES CON FUNCIONALIDADES MODULABLES/ | |
dc.relation.uri | https://doi.org/10.1039/D0CS00109K | es_ES |
dc.title | Controlled Binding of Organic Guests by Stimuli-Responsive Macrocycles | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | Chemical Society Reviews | es_ES |
UDC.volume | 49 | es_ES |
UDC.issue | 12 | es_ES |
UDC.startPage | 3834 | es_ES |
UDC.endPage | 3862 | es_ES |
dc.identifier.doi | 10.1039/D0CS00109K |
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