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The role of ligand to metal charge-transfer states on the luminescence of Europium complexes with 18-membered macrocyclic ligands
(Royal Society of Chemistry, 2019-02-27)
[Abstract] We report a detailed study of the photophysical properties of EuIII and TbIII complexes with two ligands based on a 3,6,10,13-tetraaza-1,8(2,6)-dipyridinacyclotetradecaphane platform containing either four ...
Reinforced Ni(ɪɪ)-Cyclam Derivatives as Dual ¹H/¹⁹F MRI Probes
(Royal Society of Chemistry, 2019-03-11)
[Abstract] Reinforced cross-bridged Ni²⁺-cyclam complexes were functionalised with pendant arms containing both amide protons and CF₃ groups that lead to a dual ¹H/¹⁹F response. The resulting complexes possess very high ...