Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions

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UDC.coleccionInvestigaciónes_ES
UDC.departamentoQuímicaes_ES
UDC.endPage1456es_ES
UDC.grupoInvQuímica Molecular e de Materiais (QUIMOLMAT)es_ES
UDC.issue12es_ES
UDC.journalTitleChemical Communicationses_ES
UDC.startPage1453es_ES
UDC.volume54es_ES
dc.contributor.authorGil-Negrete, José M.
dc.contributor.authorPérez Sestelo, José
dc.contributor.authorSarandeses, Luis A.
dc.date.accessioned2018-06-13T12:03:31Z
dc.date.embargoEndDate2019-01-12es_ES
dc.date.embargoLift2019
dc.date.issued2018-02-11
dc.description.abstract[Abstract] Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in quantitative yield and can be stored for up to several weeks. These reagents show excellent reactivity in palladium-catalyzed cross-coupling reactions with organic electrophiles.es_ES
dc.description.sponsorshipMinisterio de Economía y Competitividad; CTQ2015-68369-Pes_ES
dc.description.sponsorshipGalicia. Consellería de Cultura, Educación e Ordenación Universitaria; GRC2014/042es_ES
dc.identifier.citationSynthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions. J. M. Gil-Negrete, J. Pérez Sestelo and L. A. Sarandeses, Chem. Commun., 2018, 54, 1453–1456.es_ES
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.urihttp://hdl.handle.net/2183/20810
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relation.urihttps://doi.org/10.1039/C7CC09344Fes_ES
dc.rights.accessRightsopen accesses_ES
dc.subjectIndium organometallicses_ES
dc.subjectCross-coupling reactionses_ES
dc.subjectPalladium catalysises_ES
dc.subjectBench-stable reagentses_ES
dc.titleSynthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactionses_ES
dc.typejournal articlees_ES
dspace.entity.typePublication
relation.isAuthorOfPublication7ee7aca5-3d9a-4ae6-8bdd-01d7f353d3b6
relation.isAuthorOfPublication6aeff1ad-a46b-4558-8ee4-08311985a32a
relation.isAuthorOfPublication.latestForDiscovery7ee7aca5-3d9a-4ae6-8bdd-01d7f353d3b6

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