Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions

Gil-Negrete, José M.; Pérez Sestelo, José; Sarandeses, Luis A.

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http://hdl.handle.net/2183/20810

Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions

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Sarandeses_Luis_2018_Synthesis_bench-stable_solid_triorganoindium_reagents_reactivity_palladium-catalyzed_cross-coupling_reactions.pdf (741.92 KB)

Identifiers

URI: http://hdl.handle.net/2183/20810

Publication date

2018-02-11

Authors

Gil-Negrete, José M.

Pérez Sestelo, José

Sarandeses, Luis A.

Bibliographic citation

Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions. J. M. Gil-Negrete, J. Pérez Sestelo and L. A. Sarandeses, Chem. Commun., 2018, 54, 1453–1456.

Abstract

[Abstract] Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in quantitative yield and can be stored for up to several weeks. These reagents show excellent reactivity in palladium-catalyzed cross-coupling reactions with organic electrophiles.