Frieiro Gomis, Pablo JuanLucio Martínez, FátimaMunín Cruz, PaulaOrtigueira Amor, Juan ManuelPereira Lorenzo, María TeresaPolo-Ces, PaulaVázquez, DignaVila, José2024-01-192018-02-19Frieiro-Gomis, P., Lucio-Martínez, F., Munín-Cruz, P., M. Ortigueira, J., Teresa Pereira, M., Polo-Ces, P., Vázquez-García, D., & M. Vila, J. (2018). The chelate-to-bridging shift of phosphane dipalladacycles: Convenient synthesis of double A-frame tetranuclear complexes. Chemical Communications, 54(21), 2662-2665. https://doi.org/10.1039/C8CC01046C1364-548Xhttp://hdl.handle.net/2183/35024[Abstract] Palladacycles of the type [Pd2(Ph2PCH2PPh2-P,P)2(C,N:C,N)] (C,N:C,N = bis(N-2,3,4-trimethoxybenzylidene)-4,4′-sulfonyldianiline or -4,4′-oxydianiline) can undergo a spontaneous slow chelate-to-bridging diphosphane coordination shift in solution. Following this strategy a tailor-made synthetic procedure was devised that culminates in isolation of double A-frame tetranuclear palladium complexes.eng© The Royal Society of Chemistryjournal articleembargoed access10.1039/C8CC01046C