Gil-Negrete, José M.Pérez Sestelo, JoséSarandeses, Luis A.2018-06-132018-02-11Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions. J. M. Gil-Negrete, J. Pérez Sestelo and L. A. Sarandeses, Chem. Commun., 2018, 54, 1453–1456.1359-73451364-548Xhttp://hdl.handle.net/2183/20810[Abstract] Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in quantitative yield and can be stored for up to several weeks. These reagents show excellent reactivity in palladium-catalyzed cross-coupling reactions with organic electrophiles.engIndium organometallicsCross-coupling reactionsPalladium catalysisBench-stable reagentsSynthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactionsjournal articleopen access