Delgado Ferreiro, IgnacioGarcía Ben, JavierGelpi, MaríaLópez-Beceiro, JorgeArtiaga, RamónZaragoza, SoniaCastro-García, SocorroSeñarís-Rodríguez, M. A.Sánchez-Andújar, ManuelBaaliña Insua, AlvaroBermúdez-García, Juan ManuelGonzález Novo, DavidFerradanes Martínez, ÁngelWalker, JulianMcMonagle, Charles JamesDixey, Richard J.C.Phillips, Anthony E.2025-12-122025-12-122025DELGADO-FERREIRO, I., FERRADANES-MARTÍNEZ, Á., GONZÁLEZ-NOVO, D., GARCÍA-BEN, J., GELPI, M., LÓPEZ-BECEIRO, J., ARTIAGA, R., WALKER, J., MCMONAGLE, C.J., DIXEY, R.J.C., PHILLIPS, A.E., ZARAGOZA, S., CASTRO-GARCÍA, S., SEÑARÍS-RODÍGUEZ, M.A., SÁNCHEZ-ANDÚJAR, M., BAALIÑA, Á. y BERMÚDEZ-GARCÍA, J.M., 2025. 3D printed barocaloric composites for environmentally friendly thermal energy management. Journal of Materials Chemistry A [en línea], vol. 13, no. 46, pp. 40179-40191. [consulta: 2 diciembre 2025]. ISSN 2050-7488, 2050-7496. DOI 10.1039/D5TA04364Fhttps://hdl.handle.net/2183/46647Funding for open access charge: Universidade da Coruña/CISUG.[Abstract] Our society is experiencing an accelerated technological transition to reach net zero emissions by 2050, where the decarbonization of heating and cooling systems is a key aspect. In this work, we describe two new solid-state barocaloric materials, [C12H25NH3]2MnCl4 and [C12H25NH3]2MnBr4, with colossal barocaloric effects of ΔS > 200 J K−1 kg−1, which are already reversible under operating pressures of 500 bar. In addition, we introduce the first 3D printable barocaloric composite using a pressure transmitting matrix and thermal conductive additives, which is formed in the shape of a heat exchange gyroid. This innovative proof-of-concept demonstrates a new strategy to enhance the thermal performance, chemical stability and technological integration of the emerging family of barocaloric compounds. In addition, we identify emerging technologies (beyond traditional refrigeration) where thermal management is critical and that match the operating temperature and pressure range of the barocaloric materials obtained here, namely, lithium-ion batteries and hydrogen fuel cells.engAttribution-NonCommercial 4.0 Internationalhttp://creativecommons.org/licenses/by-nc/4.0/3D printBarocaloric compositesThermal energyjournal articleopen access10.1039/D5TA04364F