Casademont-Viñas, MiquelCapolat, DanielQuesada-Ramírez, AriannaReinfelds, MatissTrimmel, GregorSanviti, MatteoMartín, JaimeGoñi, Alejandro R.Kirchartz, ThomasCampoy-Quiles, Mariano2025-12-112025-12-112024-06-03J. Mater. Chem. A, 2024,12, 16716-167282050-7496https://hdl.handle.net/2183/46635[Abstract]: Wide band-gap organic solar cells are gaining interest due to their applications in emergent light-harvesting technologies such as underwater photovoltaics, multi-junction solar cells, or indoor photovoltaics. In this work, a combinatorial screening approach is used to explore binary combinations of three wide band-gap donors (PTQ10, PM6, and D18) and three wide band-gap acceptors (PMI-FF-PMI, O-IDFBR, and IO-4Cl) deposited from solution in two solvents (CB and CF). In total, 18 combinations are blade-coated with active layers exhibiting a thickness gradient generating solar cells with 12 different thicknesses. PTQ10:IO-4Cl and PTQ10:O-IDFBR are the most efficient blends with efficiencies of 7.31% and 6.87%, respectively. The voltage loss analysis shows that PTQ10-based devices exhibit the lowest non-radiative voltage losses, whereby the PTQ10:O-IDFBR combination has the lowest voltage loss of all studied blends, with a remarkably high open-circuit voltage (Voc) of 1.35 V. Due to their high performance and Voc, PTQ10:O-IDFBR devices were also studied for indoor light harvesting, achieving an efficiency of 22.6% and a Voc of 1.21 V under 560 lux indoor illumination. To the best of our knowledge, this indoor Voc value is the highest achieved in the field of indoor organic photovoltaics.engAttribution 4.0 Internationalhttp://creativecommons.org/licenses/by/4.0/journal articleopen accesshttps://doi.org/10.1039/D4TA01944J