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http://hdl.handle.net/2183/170 Kinetic and Equilibrium Study of the Reaction of Nitroprusside and Hydroxide Ions: Influence of Ionic Strength Using Pitzer Model
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International journal of chemical kinetics,2004, vol. 36, 12, p.650-660
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[Abstract] A kinetic and equilibrium study of the addition reaction of hydroxide ions to nitroprusside has been carried out in this paper. Rate and equilibrium constants at different salt concentrations (up to 4 mol/kg) were obtained and the influence of ionic strength was studied by means of Pitzer equations. This model is of special interest because it is able to explain the experimental behaviour at high ionic strength, when Debye-Huckel limiting law is no longer valid.
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Published in International journal of chemical kinetics