Near Room Temperature Dielectric Transition in the Perovskite Formate Framework [(CH₃)₂NH₂][Mg(HCOO)₃]

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UDC.coleccionInvestigaciónes_ES
UDC.departamentoQuímicaes_ES
UDC.departamentoEnxeñaría Naval e Industriales_ES
UDC.grupoInvQuímica Molecular e de Materiais (QUIMOLMAT)es_ES
UDC.grupoInvPropiedades Térmicas e Reolóxicas de Materiais (PROTERM)es_ES
dc.contributor.authorPato Doldán, Breogán
dc.contributor.authorSánchez-Andújar, Manuel
dc.contributor.authorGómez Aguirre, Lilián Claudia
dc.contributor.authorYáñez, Susana
dc.contributor.authorLópez-Beceiro, Jorge
dc.contributor.authorGracia-Fernández, Carlos
dc.contributor.authorHaghighirad, A. A.
dc.contributor.authorRitter, F.
dc.contributor.authorCastro-García, Socorro
dc.contributor.authorSeñarís-Rodríguez, M. A.
dc.date.accessioned2015-02-09T15:35:32Z
dc.date.available2015-02-09T15:35:32Z
dc.date.issued2012-05
dc.description.abstract[Abstract] We report that the hybrid organic–inorganic compound [(CH₃)₂NH₂][Mg(HCOO)₃] shows a marked dielectric transition around Tₜ ∼ 270 K, associated to a structural phase transition from SG R[3 with combining macron]c (centrosymmetric) to Cc (non-centrosymmetric). This is the highest Tₜ reported so far for a perovskite-like formate that is thus a promising candidate to display electric order very close to room temperature.es_ES
dc.description.sponsorshipXunta de Galicia; PGIDIT10PXB103272PR
dc.description.sponsorshipMinisterio de Economia y Competitividad; MAT2010-21342-C02-01es_ES
dc.identifier.citationPato-Doldán B, Sánchez-Andújar M, Gómez-Aguirre LC, Yáñez-Vilar S, López-Beceiro J, Gracia-Fernández C, et al. Near room temperature dielectric transition in the perovskite formate framework [(CH₃)₂NH₂][Mg(HCOO)₃]. Physical Chemistry Chemical Physics. 2012;14(24):8498-501es_ES
dc.identifier.issn1463-9084
dc.identifier.urihttp://hdl.handle.net/2183/14037
dc.language.isoenges_ES
dc.publisherThe Royal Society of Chemistryes_ES
dc.relation.urihttp://dx.doi.org/10.1039/c2cp40564des_ES
dc.rights.accessRightsopen accesses_ES
dc.subjectHybrid organic–inorganic compoundes_ES
dc.subjectDielectric propertieses_ES
dc.subjectMetal–organic frameworkses_ES
dc.subjectNanoporouses_ES
dc.subjectPerovskite structurees_ES
dc.titleNear Room Temperature Dielectric Transition in the Perovskite Formate Framework [(CH₃)₂NH₂][Mg(HCOO)₃]es_ES
dc.typejournal articlees_ES
dspace.entity.typePublication
relation.isAuthorOfPublication1105a821-5f59-4e06-90bb-77324fa7b419
relation.isAuthorOfPublicationa3cd7858-ed46-4b7e-85ad-bf86628af713
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relation.isAuthorOfPublication.latestForDiscovery1105a821-5f59-4e06-90bb-77324fa7b419

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