Use this link to cite:

http://hdl.handle.net/2183/40666

Thermal Decomposition of [AH][M(HCOO)₃] Perovskite-Like Formates

Thumbnail Image

Files

SenarisRodriguez_MA_2021_Thermal_decomposition_perovskite_like_formates.pdf (2.16 MB)

Identifiers

URI: http://hdl.handle.net/2183/40666
DOI: 10.3390/solids2020011

Publication date

2021-05-02

Authors

Gómez Aguirre, Lilián Claudia
Otero-Canabal, Jorge
Pato Doldán, Breogán

Advisors

Other responsabilities

Journal Title

Bibliographic citation

Gómez-Aguirre, L. C., Otero-Canabal, J., Sánchez-Andújar, M., Señarís-Rodríguez, M. A., Castro-García, S., & Pato-Doldán, B. (2021). Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates. Solids, 2(2), 165-176. https://doi.org/10.3390/solids2020011

Type of academic work

Academic degree

Abstract

[Abstract] A systematic study of the thermal decomposition of hybrid perovskites of formula [AH][M(HCOO)₃] under inert atmosphere was performed by means of thermogravimetry and simultaneous infrared spectroscopy of the evolved gases. The influence of: (i) the metal ion of the [M(HCOO)₃]‾ framework and (ii) the guest [AH]⁺ cation, in the composition of the final residue was evaluated. In this work, it has been demonstrated that these materials can be used as precursors of metal or metal-oxide compounds—obtained free of carbon—, and that the composition of the final residue is determined by the standard reduction potential of the metal cation of the framework.

Description

This article belongs to the Special Issue Feature Papers of Solids 2021

Keywords

Coordination polymers Hybrid perovskites Thermolysis Formates

Editor version

https://doi.org/10.3390/solids2020011

Rights

Atribución 4.0 Internacional

Collections

Investigación (FCIE)
Atribución 4.0 Internacional

Except where otherwise noted, this item's license is described as Atribución 4.0 Internacional