A simple solvothermal synthesis of MFe2O4 (M=Mn, Co and Ni) nanoparticles

Abstract

[Abstract] Nanoparticles of MFe2O4 (M=Mn, Co and Ni), with diameters ranging from 5 to 10 nm, have been obtained through a solvothermal method. In this synthesis, an alcohol (benzyl alcohol or hexanol) is used as both a solvent and a ligand; it is not necessary, therefore, to add a surfactant, simplifying the preparation of the dispersed particles. We have studied the influence of the synthetic conditions (temperature, time of synthesis and nature of solvent) on the quality of the obtained ferrites and on their particle size. In this last aspect, we have to highlight that the solvent plays an important role on the particle size, obtaining the smallest diameters when hexanol was used as a solvent. In addition, the magnetic properties of the obtained compounds have been studied at room temperature (RT). These compounds show a superparamagnetic behaviour, as was expected for single domain nanoparticles, and good magnetization values. The maxima magnetization values of the MFe2O4 samples are quite high for such small nanoparticles; this is closely related to the high crystallinity of the particles obtained by the solvothermal method.