Stimuli-responsive metal-directed self-assembly of a ring-in-ring complex

Alvariño Bouza, Cristina; Platas-Iglesias, Carlos; Blanco, Víctor; García, Marcos D.; Peinador, Carlos; Quintela López, José María

Use this link to cite:

http://hdl.handle.net/2183/24234

Stimuli-responsive metal-directed self-assembly of a ring-in-ring complex

Files

PlatasIglesias_Carlos_2016_Stimuli-responsive_metal-directed_self-assembly_ring-in-ring_complex.pdf (1.46 MB)

Identifiers

URI: http://hdl.handle.net/2183/24234

Publication date

2016-06-06

Authors

Alvariño Bouza, Cristina

Platas-Iglesias, Carlos

Blanco, Víctor

García, Marcos D.

Peinador, Carlos

Quintela López, José María

Bibliographic citation

C. Alvariño, C. Platas-Iglesias, V. Blanco, M. D. García, C. Peinador and J. M. Quintela, Dalt. Trans., 2016, 45, 11611–11615.

Abstract

[Abstract] Concentration, temperature and/or solvent polarity control the speciation on the metal-directed self-assembly of a ditopic pyridyl ligand L with cis-protected Pd(II) metal centers. This results into a controllable dynamic system, involving a [Pd2L2]6+ metallacycle and a [Pd4L4]12+ ring-in-ring complex.