The role of the capping bond effect on pyclen natY3+/90Y3+ chelates: full control of the regiospecific N-functionalization makes the difference

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UDC.coleccionInvestigaciónes_ES
UDC.departamentoQuímicaes_ES
UDC.endPage9537es_ES
UDC.grupoInvReactividade Química e Fotorreactividade (REACT!)es_ES
UDC.issue69es_ES
UDC.journalTitleChemical Communicationses_ES
UDC.startPage9534es_ES
UDC.volume53es_ES
dc.contributor.authorLe Fur, Mariane
dc.contributor.authorBeyler, Maryline
dc.contributor.authorMolnár, Enikö
dc.contributor.authorFougère, Olivier
dc.contributor.authorEsteban-Gómez, David
dc.contributor.authorTircsó, Gyula
dc.contributor.authorPlatas-Iglesias, Carlos
dc.contributor.authorLepareur, Nicolas
dc.contributor.authorRousseaux, Olivier
dc.contributor.authorTripier, Raphaël
dc.date.accessioned2018-11-28T11:47:49Z
dc.date.available2018-11-28T11:47:49Z
dc.date.issued2017-09-07
dc.description.abstract[Abstract] Thanks to a smart regiospecific N-functionalization, a pyclen based ligand bearing one picolinate and two acetate arms organized in a dissymmetric manner was synthesized for Y3+ complexation, and compared to its symmetric analogue. The nature of the capping bonds around the metal coordination environment has a dramatic effect on the properties of the chelate, the natY3+ and 90Y3+ dissymmetric derivatives presenting enhanced thermodynamic stability and kinetic inertness.es_ES
dc.description.sponsorshipHungarian Scientific Research Fund; NKFIH K-120224es_ES
dc.identifier.citationThe role of the capping bond effect on pyclen natY3+/90Y3+ chelates: full control of the regiospecific N-functionalization makes the difference. M. Le Fur, M. Beyler, E. Molnár, O. Fougère, D. Esteban-Gómez, G. Tircsó, C. Platas-Iglesias, N. Lepareur, O. Rousseaux and R. Tripier, Chem. Commun., 2017, 53, 9534–9537.es_ES
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.urihttp://hdl.handle.net/2183/21395
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relation.urihttps://doi.org/10.1039/C7CC05088Ges_ES
dc.rights.accessRightsopen accesses_ES
dc.subjectThermodynamic stabilityes_ES
dc.subjectDFT calculationses_ES
dc.subjectYttrium complexeses_ES
dc.subjectPyclen ligandses_ES
dc.subjectRadiotherapyes_ES
dc.titleThe role of the capping bond effect on pyclen natY3+/90Y3+ chelates: full control of the regiospecific N-functionalization makes the differencees_ES
dc.typejournal articlees_ES
dspace.entity.typePublication
relation.isAuthorOfPublicationf30c18a2-108e-44d6-a7d2-b3b4e378509b
relation.isAuthorOfPublication8bb35ae5-5c53-4d41-87b8-949a82445202
relation.isAuthorOfPublication.latestForDiscoveryf30c18a2-108e-44d6-a7d2-b3b4e378509b

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