Kinetic and Equilibrium Study of the Reaction of Nitroprusside and Hydroxide Ions: Influence of Ionic Strength Using Pitzer Model
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Kinetic and Equilibrium Study of the Reaction of Nitroprusside and Hydroxide Ions: Influence of Ionic Strength Using Pitzer ModelDate
2004Citation
International journal of chemical kinetics,2004, vol. 36, 12, p.650-660
Abstract
[Abstract] A kinetic and equilibrium study of the addition reaction of hydroxide ions to nitroprusside has
been carried out in this paper. Rate and equilibrium constants at different salt concentrations
(up to 4 mol/kg) were obtained and the influence of ionic strength was studied by means of
Pitzer equations. This model is of special interest because it is able to explain the
experimental behaviour at high ionic strength, when Debye-Huckel limiting law is no longer
valid.
Keywords
Nitroprusside
Hydroxide ions
Pitzer model
Hydroxide ions
Pitzer model
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Published in International journal of chemical kinetics
ISSN
1097-4601