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Subcellular duplex DNA and G‐quadruplex interaction profiling of a hexagonal PtII metallacycle
(Wiley, 2019-04-19)
[Abstract] Metal‐driven self‐assembly afforded a multitude of fascinating supramolecular coordination complexes (SCCs) with applications as catalysts, host–guest, and stimuli‐responsive systems. However, the interest in ...
Anti-Inflammatory Effects of 5α,8α-Epidioxycholest-6-en-3β-ol, a Steroidal Endoperoxide Isolated from Aplysia depilans, Based on Bioguided Fractionation and NMR Analysis
(MDPI, 2019-06-03)
[Abstract:] Sea hares of "Aplysia" genus are recognized as a source of a diverse range of metabolites. 5α,8α-Endoperoxides belong to a group of oxidized sterols commonly found in marine organisms and display several ...
Marine Organisms from the Yucatan Peninsula (Mexico) as a Potential Natural Source of Antibacterial Compounds
(MDPI, 2020-07-18)
[Abstract] A total of 51 sponges (Porifera) and 13 ascidians (Chordata) were collected on the coast of the Yucatan Peninsula (Mexico) and extracted with organic solvents. The resulting extracts were screened for antibacterial ...
In Vitro and In Vivo Assessment of the Efficacy of Bromoageliferin, an Alkaloid Isolated from the Sponge Agelas dilatata, against Pseudomonas aeruginosa
(MDPI, 2020-06-23)
[Abstract] The pyrrole-imidazoles, a group of alkaloids commonly found in marine sponges belonging to the genus Agelas, display a wide range of biological activities. Herein, we report the first chemical study of the ...
Relative Configuration of Micrograms of Natural Compounds Using Proton Residual Chemical Shift Anisotropy
(Nature, 2020-09-01)
[Abstract] 3D molecular structure determination is a challenge for organic compounds or natural products available in minute amounts. Proton/proton and proton/carbon correlations yield the constitution. J couplings and ...
Natural Products from Antarctic Colonial Ascidians of the Genera Aplidium and Synoicum: Variability and Defensive Role
(Molecular Diversity Preservation International, 2012)
Ascidians have developed multiple defensive strategies mostly related to physical, nutritional or chemical properties of the tunic. One of such is chemical defense based on secondary metabolites. We analyzed a series of ...
Development of Antibacterial Steel Surfaces Through Laser Texturing
(AIP Publishing, 2020-09-22)
[Abstract] The aim of the present study was to develop novel antibacterial touch surfaces through the laser texturing optimization of stainless steel. A wide range of laser fluence (2.11 J/cm2–5.64 J/cm2) and scanning ...
Advances in Cross-Coupling Reactions [Editorial]
(MDPI, 2020-10-01)
[Abstract] Cross-coupling reactions stand among the most important reactions in chemistry. Nowadays, they are a highly valuable synthetic tool used for the preparation of a wide variety of organic compounds, from natural ...
Raman Spectroscopy Studies on the Barocaloric Hybrid Perovskite [(CH₃)₄N][Cd(N₃)₃]
(MDPI, 2020-10-16)
[Abstract] Temperature-dependent Raman scattering and differential scanning calorimetry were applied to the study of the hybrid organic-inorganic azide-perovskite [(CH₃)₄N][Cd(N₃)₃], a compound with multiple structural ...
Thinking Outside the Blue Box: From Molecular to Supramolecular PH-Responsiveness
(Royal Society of Chemistry, 2019-10-23)
[Abstract] We present herein the development of a new polycationic cyclophane: the “red box”, second in a series of hydrazone-based analogues of the well-known organic receptor cyclobis(paraquat-p-phenylene)cyclophane ...