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Magnetoelectric behavior in the complex CaMn7O12 perovskite
(Elsevier, 2009)
[Abstract] We report a magnetoelectric effect in the double perovskite CaMn7O12, that shows a complex magnetic behavior below 90 K with two magnetic phases coexisting (one ferrimagnetic and the other modulated). A second ...
Amino Acid–Viologen Hybrids: Synthesis, Cucurbituril Host–Guest Chemistry, and Implementation on the Production of Peptides
(American Chemical Society, 2021-12-10)
[Abstract] We present herein the development of a series of viologen–amino acid hybrids, obtained in good yields either by successive alkylations of 4,4′-bipyridine, or by Zincke reactions followed by a second alkylation ...
Natural Products from Antarctic Colonial Ascidians of the Genera Aplidium and Synoicum: Variability and Defensive Role
(Molecular Diversity Preservation International, 2012)
Ascidians have developed multiple defensive strategies mostly related to physical, nutritional or chemical properties of the tunic. One of such is chemical defense based on secondary metabolites. We analyzed a series of ...
Development of Antibacterial Steel Surfaces Through Laser Texturing
(AIP Publishing, 2020-09-22)
[Abstract] The aim of the present study was to develop novel antibacterial touch surfaces through the laser texturing optimization of stainless steel. A wide range of laser fluence (2.11 J/cm2–5.64 J/cm2) and scanning ...
In Vitro and In Vivo Assessment of the Efficacy of Bromoageliferin, an Alkaloid Isolated from the Sponge Agelas dilatata, against Pseudomonas aeruginosa
(MDPI, 2020-06-23)
[Abstract] The pyrrole-imidazoles, a group of alkaloids commonly found in marine sponges belonging to the genus Agelas, display a wide range of biological activities. Herein, we report the first chemical study of the ...
Synthesis of Acetylhomoagmatine
(Molecular Diversity Preservation International, 2006)
The first total synthesis of acetylhomoagmatine, a natural product isolated form the methanolic extracts from the sponge Cliona celata, is performed in four steps in a very high yield.
Raman Spectroscopy Studies on the Barocaloric Hybrid Perovskite [(CH₃)₄N][Cd(N₃)₃]
(MDPI, 2020-10-16)
[Abstract] Temperature-dependent Raman scattering and differential scanning calorimetry were applied to the study of the hybrid organic-inorganic azide-perovskite [(CH₃)₄N][Cd(N₃)₃], a compound with multiple structural ...
Thinking Outside the Blue Box: From Molecular to Supramolecular PH-Responsiveness
(Royal Society of Chemistry, 2019-10-23)
[Abstract] We present herein the development of a new polycationic cyclophane: the “red box”, second in a series of hydrazone-based analogues of the well-known organic receptor cyclobis(paraquat-p-phenylene)cyclophane ...
Enigmazole C: A Cytotoxic Macrocyclic Lactone and Its Ring-Opened Derivatives from a New Species of Homophymia Sponge
(American Chemical Society, 2022-03-02)
[Abstract] A new macrolide, enigmazole C (1), and two additional analogues, enigmazoles E (2) and D (3), were obtained from a new species of the Homophymia genus as part of an ongoing discovery program at PharmaMar to study ...
Connection of Isolated Stereoclusters by Combining 13C-RCSA, RDC, and J-Based Configurational Analyses and Structural Revision of a Tetraprenyltoluquinol Chromane Meroterpenoid from Sargassum muticum
(MDPI, 2022)
[Abstract] The seaweed Sargassum muticum, collected on the southern coast of Galicia, yielded a tetraprenyltoluquinol chromane meroditerpene compound known as 1b, whose structure is revised. The relative configuration of ...
