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Tautomerization of 2-acetylcyclohexanone in assemblies of cationic surfactants. Nitrosation of the enol.
(Royal Society of Chemistry, 2005)
The kinetic study of the keto-enol interconversion of 2-acetylcyclohexanone (ACHE) has been performed in organic solvents such as dimethylsulfoxide (DMSO), 1-propanol (1-PrOH), 2-propanol (2-PrOH), methanol (MeOH), dioxane, ...
Solvent Effects versus Concentration Effects in determining Rates of Base-catalysed Keto-enol Tautomerization
(Royal Society of Chemistry, 2005)
Solvent effects of homogeneous media (such as solvent-water mixtures) in chemical reactivity may be interpreted as due to solvent polarity and/or molecular structure of solvent molecules. In microheterogeneous media (such ...
Iron(III) complexation by Vanchrobactin, a siderophore of the bacterial fish pathogen Vibrio anguillarum
(Royal Society of Chemistry, 2011-05)
The bacterial fish pathogen Vibrio anguillarum serotype O2 strain RV22 produces the mono catecholate siderophore Vanchrobactin (Vb) under conditions of iron deficiency. Vb contains two potential bidentate coordination ...
Fluorescence study of tetracaine–cyclodextrin inclusion complexes
(Taylor and Francis Ltd., 2010-04)
The steady-state fluorescence emission from the local anaesthetic tetracaine (TCA) in water-solvent mixtures and in the presence of α-, β- and γ-cyclodextrin (CD) was investigated at various pH values. Emission was observed ...
Micellar effects on aromatic esters hydrolysis
(Elsevier, 2014-07)
The alkaline hydrolysis of two aromatic esters, 2-naphthyl acetate (2NA) and phenyl acetate (PhA) has been tackled in this work. The reaction has been followed in water and in the presence of cationic surfactants with ...
A further study of acetylacetone nitrosation
(Royal Society of Chemistry, 2013-02)
The nitrosation of acetylacetone (AcAc) has been revised in an aqueous acid medium of perchloric acid and buffers of mono-, di-, or tri-chloroacetic acid. The results show that in the presence of buffers, under conditions ...
Potentiometric characterisation of cyclodextrin inclusion complexes of local anaesthetics
(Taylor and Francis Ltd., 2011-09)
The complexation of several local anaesthetics by β and γ-cyclodextrins was studied by potentiometry with glass electrode. Tetracaine and dibucaine complexation constants were determined at 25°C in the presence of 0.1 M ...