• Inert macrocyclic Eu3+ complex with affirmative paraCEST features 

      Gambino, Tanja; Valencia, Laura; Pérez-Lourido, Paulo; Esteban-Gómez, David; Zaiss, Moritz; Platas-Iglesias, Carlos; Angelovski, Goran (Royal Society of Chemistry, 2020-06-21)
      [Abstract]: We report on a macrocyclic platform based on an 18-membered macrocycle that forms kinetically highly inert paramagnetic complexes and possesses an excellent outlook for the development of bioresponsive paraCEST ...
    • Probing Tyrosine Nitration with a Small TbIII-Metallopeptide 

      Sánchez-Fernández, Rosalía; Sánchez-Temprano, Agustín; Esteban-Gómez, David; Pazos, Elena (Wiley, 2023-06-06)
      [Abstract] Tyrosine nitration, a post-translational modification (PTM) that takes place under nitrosative stress conditions, occurs through a non-enzymatic peroxynitrite-mediated reaction. Although protein nitration has ...
    • Spectrally undiscerned isomers might lead to erroneous determination of water exchange rates of paraCEST Eu(III) agents 

      Cakic, Nevenka; Tickner, Ben; Zaiss, Moritz; Esteban-Gómez, David; Platas-Iglesias, Carlos; Angelovski, Goran (American Chemical Society, 2017-07-17)
      [Abstract] We report a detailed study of the solution structure and water exchange rate of a Eu(III) complex with the cyclen-based ligand L1, containing (S)-2-(2-acetamido)-3-(4 (trifluoromethyl)phenyl)propanoate pendant ...