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Stereoselective synthesis of alpha-monofluorinated phosphonate mimetics of naturally occurring phosphoserine and phosphothreonine, via electrophilic fluorination of lithiated bis-lactim ethers
(The Royal Society of Chemistry, 2002-06-25)
[Abstract] Electrophilic fluorinations of lithiated bis-lactim ethers derived from cyclo-[L-AP4-D-Val] allow a direct access to alpha-monofluorinated phosphonate mimetics of naturally occurring phosphoserine and phosphothreonine, ...
DLPNO-CCSD(T) and DFT Study of the Acetate-Assisted C–H Activation of Benzaldimine at [RuCl2(p-cymene)]2: The Relevance of Ligand Exchange Processes at Ruthenium(II) Complexes in Polar Protic Media
(Royal Society of Chemistry (Gran Bretaña), 2024-04-25)
[Abstract] To gain mechanistic insights into the acetate-assisted cyclometallations of arylimines promoted by [RuCl2(p-cymene)]2 in polar protic media, DFT geometry optimizations (with M06 and ωB97X-D3 functionals and the ...