Thermal Decomposition of [AH][M(HCOO)₃] Perovskite-Like Formates

Gómez-Aguirre, L. C., Otero-Canabal, J., Sánchez-Andújar, M., Señarís-Rodríguez, M. A., Castro-García, S., & Pato-Doldán, B. (2021). Thermal Decomposition of [AH][M(HCOO)3] Perovskite-Like Formates. Solids, 2(2), 165-176. https://doi.org/10.3390/solids2020011

Abstract

[Abstract] A systematic study of the thermal decomposition of hybrid perovskites of formula [AH][M(HCOO)₃] under inert atmosphere was performed by means of thermogravimetry and simultaneous infrared spectroscopy of the evolved gases. The influence of: (i) the metal ion of the [M(HCOO)₃]‾ framework and (ii) the guest [AH]⁺ cation, in the composition of the final residue was evaluated. In this work, it has been demonstrated that these materials can be used as precursors of metal or metal-oxide compounds—obtained free of carbon—, and that the composition of the final residue is determined by the standard reduction potential of the metal cation of the framework.