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Viologen–cucurbituril host/guest chemistry – redox control of dimerization versus inclusion
dc.contributor.author | Dalvand, Parastoo | |
dc.contributor.author | Nchimi Nono, Katia | |
dc.contributor.author | Shetty, Dinesh | |
dc.contributor.author | Benyettou, Farah | |
dc.contributor.author | Asfari, Zouhair | |
dc.contributor.author | Platas-Iglesias, Carlos | |
dc.contributor.author | Olson, Mark Anthony | |
dc.contributor.author | Trabolsi, Ali | |
dc.contributor.author | Elhabiri, Mourad | |
dc.date.accessioned | 2022-01-18T13:40:00Z | |
dc.date.available | 2022-01-18T13:40:00Z | |
dc.date.issued | 2021-09-02 | |
dc.identifier.citation | P. Dalvand, K. Nchimi Nono, D. Shetty, F. Benyettou, Z. Asfari, C. Platas-Iglesias, M. A. Olson, A. Trabolsi and M. Elhabiri, Viologen–cucurbituril host/guest chemistry – redox control of dimerization versus inclusion, 2021, 11, 29543–29554. | es_ES |
dc.identifier.issn | 2046-2069 | |
dc.identifier.uri | http://hdl.handle.net/2183/29412 | |
dc.description.abstract | [Abstract] Two calix[4]arene systems, C234+ and C244+ – where 2 corresponds to the number of viologen units and 3–4 corresponds to the number of carbon atoms connecting the viologen units to the macrocyclic core – have been synthesized and led to the formation of [3]pseudorotaxanes when combined with either CB[7] or CB[8]. The [3]pseudorotaxanes spontaneously dissociate upon reduction of the bipyridinium units as the result of intramolecular dimerization of the two face-to-face viologen radical cations. CB[7] and CB[8]-based [2]pseudorotaxanes containing monomeric viologen guest model compounds, MC32+ and MC4+, do not undergo decomplexation and dimerization following electrochemical reduction of their bipyridinium units. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation.uri | DOI https://doi.org/10.1039/D1RA05488K | es_ES |
dc.rights | Atribución-NoComercial 3.0 España | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/es/ | * |
dc.title | Viologen–cucurbituril host/guest chemistry – redox control of dimerization versus inclusion | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | RSC Advances | es_ES |
UDC.volume | 11 | es_ES |
UDC.issue | 47 | es_ES |
UDC.startPage | 29543 | es_ES |
UDC.endPage | 29554 | es_ES |
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