GI-REACT! - Artigos: Envíos recentes
Mostrando ítems 1-5 de 107
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O-versus S-Metal Coordination of the Thiocarboxylate Group: An NMR Study of the Two Tautomeric Forms of the Ga(III)-Photoxenobactin E Complex
(American Chemical Society, 2024-02-22)[Abstract] Photoxenobactin E (1) is a natural product with an unusual thiocarboxylic acid terminus recently isolated from an entomopathogenic bacterium. The biosynthetic gene cluster associated with photoxenobactin E, and ... -
Understanding the Mechanism of Base-Assisted Decomposition of (N-halo),N-alkylalcoholamines
(Royal Society of Chemistry (Gran Bretaña), 2003-09-29)[Abstract] The base-assisted decomposition of (N-X),N-methylethanolamine (X = Cl, Br) takes place mainly through two concurrent processes: a fragmentation and an intramolecular elimination. The global process follows second ... -
A Theoretical Study on the Mechanism of the Base-Promoted Decomposition of N-chloro,N-methylethanolamine
(Royal Society of Chemistry (Gran Bretaña), 2009-02-09)[Abstract] The first step of the base-promoted decomposition of N-chloro,N-methylethanolamine in aqueous solution (CH3N(Cl)CH2CH2OH + HO−→ imine + Cl− + H2O (+ CH2O) → amine + aldehyde) is investigated at the MP2/6-31++G(d,p) ... -
Solar-Assisted Photodegradation of Pesticides Over Pellet-Shaped TiO2-Kaolin Catalytic Macrocomposites at Semi-pilot-Plant Scale: Elucidation of Photo-Mechanisms and Water Matrix Effect
(Elsevier, 2023-10-11)[Abstract] The behavior of novel pellet-shaped bulky titania-kaolin photocatalysts is herein evaluated for its application in the solar-assisted photocatalytic treatment of a bio-recalcitrant pesticide mix (imidacloprid, ... -
Plastic Debris in Lakes and Reservoirs
(Springer Nature, 2023)[Abstract] Plastic debris is thought to be widespread in freshwater ecosystems globally1. However, a lack of comprehensive and comparable data makes rigorous assessment of its distribution challenging2,3. Here we present ...