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Versatile Macrocyclic Platform for the Complexation of [ⁿᵃᵗY/⁹⁰Y]Yttrium and Lanthanide Ions
(American Chemical Society, 2022-04-14)
[Abstract] We report a macrocyclic ligand (H3L6) based on a 3,6,10,13-tetraaza-1,8(2,6)-dipyridinacyclotetradecaphane platform containing three acetate pendant arms and a benzyl group attached to the fourth nitrogen atom ...
Dimer formation of GdDO3A-arylsulfonamide complexes causes loss of pH-dependency of relaxivity
(Royal Society of Chemistry, 2017-11-06)
[Abstract] Gadolinium(III) complexes with pH-dependent relaxivities have been proposed as responsive magnetic resonance imaging (MRI) contrast agents (CA) for mapping of pH value in living subjects. The latter is clinically ...
Thermodynamic Stability of Mn(II) Complexes with Aminocarboxylate Ligands Analyzed Using Structural Descriptors
(ACS, 2022-08-22)
[Abstract] We present a quantitative analysis of the thermodynamic stabilities of Mn(II) complexes, defined by the equilibrium constants (log KMnL values) and the values of pMn obtained as −log[Mn]free for total metal and ...
The Role of Personality in the Adoption of Pro-Environmental Behaviors through the Lens of the Value-Belief-Norm Theory
(MDPI, 2023-08-24)
[Abstract] The present study investigated citizens’ self-reported pro-environmental behaviors by adopting a survey and bootstrapping via structural equation modeling for five different personality traits. Adopting one ...
Mechanical Stability Is Key for Large-Scale Implementation of Photocatalytic Surface-Attached Film Technologies in Water Treatment
(Frontiers, 2021-10-18)
[Abstract] Replacement of classical tertiary water treatment by chemical-free sunlight-driven photocatalytic units has been often proposed. Photocatalysts are required to be cost-effective, inert, chemically stable, reusable, ...
Inactivation of E. Coli and S. Aureus by Novel Binary Clay/Semiconductor Photocatalytic Macrocomposites Under UVA and Sunlight Irradiation
(Elsevier, 2023-09-08)
[Abstract] The disinfection efficiency of several novel photocatalytic macrocomposites made of Ecuadorian clay mixed with two semiconductor materials (TiO2, ZnO) has been evaluated with Staphylococcus aureus and Escherichia ...
Removal of Paracetamol in the Presence of Iron(III) Complexes of Glutamic and Lactic Acid in Aqueous Solution Under NUV Irradiation
(Elsevier, 2021-01-05)
[Abstract] Low concentrations of drugs and their metabolites occurring on the aquatic environment are of significant concern due to their potential effects. This work reports on the removal from aqueous solution, of ...
Degradation of Aqueous Ketoprofen by Heterogeneous Photocatalysis Using Bi2S3/TiO2–Montmorillonite Nanocomposites Under Simulated Solar Irradiation
(Elsevier, 2018-09-13)
[Abstract] The photocatalytic degradation of Ketoprofen (KP), 2-(3-benzoylphenyl)-propionic acid was studied under near UV–Vis irradiation (NUV-Vis) using supported photocatalysts. Bi2S3/TiO2-montmorillonite (Bi2S3/TiO2-Mt) ...
Simulated Sunlight Photodegradation of 2-Mercaptobenzothiazole by Heterogeneous Photo-Fenton Using a Natural Clay Powder
(Elsevier, 2018-02-24)
[Abstract] The efficiency of 2-mercaptobenzothiazole (MBT) degradation by heterogeneous photo-Fenton process using local natural clay powder (NCP) is described. Experiments were conducted at natural pH with a batch reactor ...
Photo-Immobilization of Proteins on Carbons
(Elsevier, 2019-11-13)
[Abstract] The photofunctionalization of three different carbons with two proteins was studied at room temperature. Water solutions of bovine serum albumin, BSA, and α-amylase, AA, were photolyzed at 21 °C in the presence ...