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Definition of the labile capping bond effect in lanthanide complexes
(Wiley, 2017-01-23)
[Abstract] Two macrocyclic ligands containing a cyclen unit, a methyl group, a picolinate arm, and two acetate pendant arms attached to two nitrogen atoms of the macrocycle either in trans (1,7-H3Medo2 ampa = 2,2′-(7-((6 ...
Spectroscopic properties of a family of mono‐ to trinuclear lanthanide complexes
(Wiley, 2017-04-10)
[Abstract] A series of mono‐, di‐, and trinuclear complexes of Eu and Tb was designed to study the influence of the number of Ln emitting centers on the luminescence properties of discrete polynuclear complexes. The complexes ...
Stable Mn2+, Cu2+ and Ln3+ complexes with cyclen-based ligands functionalized with picolinate pendant arms
(Royal Society of Chemistry, 2015-01-20)
[Abstract] In this study we present the results of the equilibrium, dissociation kinetics, DFT and X - ray crystallographic studies performed on the complexes of metal ions of biomedical importance (Mn 2+ , Cu 2+ and ...