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Thermophysical Characterization of TFSI Based Ionic Liquid and Lithium Salt Mixtures
dc.contributor.author | Fernández-Míguez, Lois | |
dc.contributor.author | Vallet, Pablo | |
dc.contributor.author | Tasende-Rodríguez, Lucía Camila | |
dc.contributor.author | Doval, Alejandro | |
dc.contributor.author | Villanueva López, María | |
dc.contributor.author | Cabeza, Óscar | |
dc.contributor.author | Varela, Luis M. | |
dc.contributor.author | Salgado, Josefa | |
dc.contributor.author | Parajó, Juan José | |
dc.date.accessioned | 2020-03-03T14:02:01Z | |
dc.date.available | 2020-03-03T14:02:01Z | |
dc.date.issued | 2019-11-14 | |
dc.identifier.citation | Fernández-Miguez, L.; Vallet, P.; Tasende-Rodríguez, L.C.; Doval, A.; Villanueva, M.; Cabeza, Ó.; Varela, L.M.; Salgado, J.; Parajó, J.J. Thermophysical Characterization of TFSI Based Ionic Liquid and Lithium Salt Mixtures. Proceedings 2019, 41, 57. https://doi.org/10.3390/ecsoc-23-06618 | es_ES |
dc.identifier.issn | 2504-3900 | |
dc.identifier.uri | http://hdl.handle.net/2183/25095 | |
dc.description | Este artigo pertence ás actas do The 23rd International Electronic Conference on Synthetic Organic Chemistry. | es_ES |
dc.description.abstract | [Abstract] The ionic liquids (ILs) doped with metal salts have become a real alternative as electrolytes for batteries, but the right choice of these compounds for reaching the adequate properties and performance is still a challenge, and strategies are therefore needed for achieving it. The thermophysical properties of IL 1-butyl-1-methylpyrrolidinium bis[(trifluoromethyl)sulfonyl]imide ([bmpyr] [TFSI]) and its mixture with bis-(trifluoromethane)-sulfonimide lithium salt (from 0.1 m to saturation level) were determined in this work. These properties are density (ρ), speed of sound (U), and corresponding derived magnitudes, such as the bulk modulus and the thermal coefficient, as well as electrical conductivity (σ) against temperature. Density shows a linear decreasing dependence with temperature and a clear increase with the addition of salt, whereas the thermal expansion coefficient increases with temperature and salt addition. Speed of sound decreases with both temperature and salt concentration, and the adiabatic compressibility calculated by means of the well-known Laplace equation increases, as expected, with temperature in all the studied cases, although a small variation with concentration was observed. Electrical conductivity increases with temperature following the Vogel–Fulcher–Tammann (VFT) equation and decreases with the addition of salt. | es_ES |
dc.description.sponsorship | This research was funded by the Spanish Ministry of Economy and Competitiveness and FEDER (Fondo Europeo de Desarrollo Regional) Program through the projects MAT2014-57943-C3-1-P, MAT2014-57943-C3-3-P, MAT2017-89239-C2-1-P as well as by Xunta de Galicia through the GRC (Grupo de Referencia Competitiva) ED431C 2016/001 project, and the Galician Network of Ionic Liquids (ReGaLIs) ED431D 2017/06. P. Vallet and J. J. Parajó are thankful for funding support from the FPI (Formación de Personal Investigador) Program from the Spanish Ministry of Science, Education and Universities and I2C postdoctoral Program of Xunta de Galicia, respectively. | es_ES |
dc.description.sponsorship | Xunta de Galicia; ED431C 2016/001 | es_ES |
dc.description.sponsorship | Xunta de Galicia; ED431D 2017/06 | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-57943-C3-1-P/ES/LIQUIDOS IONICOS DOPADOS CON SALES COMO ELECTROLITOS AVANZADOS PARA DISPOSITIVOS ELECTROQUIMICOS Y FOTONICOS | |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-57943-C3-3-P/ES/APLICACION DE LIQUIDOS IONICOS DOPADOS CON SALES COMO ELECTROLITOS AVANZADOS PARA DISPOSITIVOS ELECTROQUIMICOS Y FOTONICOS | |
dc.relation | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/MAT2017-89239-C2-1-P/ES/MATERIALES INTELIGENTES PARA LOS RETOS ELECTROQUIMICOS Y FOTONICOS: LIQUIDOS IONICOS E IONOGELES HIBRIDOS | |
dc.relation | info:eu-repo/grantAgreement/Xunta de Galicia/2016/ED431C 2016%001/ES-GA | |
dc.relation | info:eu-repo/grantAgreement/Xunta de Galicia/2017/ED431D 2017%06/ES-GA | |
dc.relation.uri | https://doi.org/10.3390/ecsoc-23-06618 | es_ES |
dc.rights | Atribución 4.0 Internacional (CC BY) | es_ES |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | * |
dc.subject | Ionic liquids | es_ES |
dc.subject | Density | es_ES |
dc.subject | Speed of sound | es_ES |
dc.subject | Electrical conductivity | es_ES |
dc.title | Thermophysical Characterization of TFSI Based Ionic Liquid and Lithium Salt Mixtures | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.access | info:eu-repo/semantics/openAccess | es_ES |
UDC.journalTitle | Proceedings | es_ES |
UDC.volume | 41 | es_ES |
UDC.issue | 1 | es_ES |
UDC.startPage | 57 | es_ES |
dc.identifier.doi | 10.3390/ecsoc-23-06618 |