Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions
Title
Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactionsDate
2018-02-11Citation
Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions. J. M. Gil-Negrete, J. Pérez Sestelo and L. A. Sarandeses, Chem. Commun., 2018, 54, 1453–1456.
Abstract
[Abstract] Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in quantitative yield and can be stored for up to several weeks. These reagents show excellent reactivity in palladium-catalyzed cross-coupling reactions with organic electrophiles.
Keywords
Indium organometallics
Cross-coupling reactions
Palladium catalysis
Bench-stable reagents
Cross-coupling reactions
Palladium catalysis
Bench-stable reagents
Editor version
ISSN
1359-7345
1364-548X
1364-548X